The metal flux: a preparative tool for the exploration of intermetallic compounds

MG Kanatzidis, R Pöttgen… - Angewandte Chemie …, 2005 - Wiley Online Library
This review highlights the use and great potential of liquid metals as exotic and powerful
solvents (ie fluxes) for the synthesis of intermetallic phases. The results presented …

Nitride chemistry of the s-block elements

DH Gregory - Coordination Chemistry Reviews, 2001 - Elsevier
The highly electropositive s-block elements combine with nitrogen in the solid state to form
some of the most ionic nitride compounds known. Also, however, these elements can …

Recent developments in nitride chemistry

R Niewa, FJ DiSalvo - Chemistry of materials, 1998 - ACS Publications
The chemistry of ternary nitrides is reviewed with special focus on developments of the last
two years (1996 and 1997). In particular, structures and properties of ternary and higher …

Structural families in nitride chemistry

DH Gregory - Journal of the Chemical Society, Dalton Transactions, 1999 - pubs.rsc.org
Recent progress in the area of nitride chemistry has been rapid and incresingly diverse.
Advances in ternary transition metal nitride research have been significant in the last several …

Synthesis and Structure of One-, Two-, and Three-Dimensional Alkaline Earth Metal Gallium Nitrides:  Sr3Ga2N4, Ca3Ga2N4, and Sr3Ga3N5

SJ Clarke, FJ DiSalvo - Inorganic chemistry, 1997 - ACS Publications
We report the structures of three new alkaline earth metal gallium nitrides synthesized as
crystals from the elements in sealed Nb tubes at 760° C using Na/Sr and Na/Ca melts as …

Sodium flux synthesis of nitrides

H Yamane, FJ DiSalvo - Progress in Solid State Chemistry, 2018 - Elsevier
Studies of the synthesis of solid state nitrides using a Na flux are reviewed. The role and
effect of Na is to solubilize polyatomic species containing nitrogen, and to lower the crystal …

Building Nitridic Networks with Phosphorus and Germanium–from GeIIP2N4 to GeIVPN3

SJ Ambach, G Krach, E Bykova, K Witthaut… - Inorganic …, 2024 - ACS Publications
Nitridophosphates and nitridogermanates attract high interest in current research due to
their structural versatility. Herein, the elastic properties of GeP2N4 were investigated by …

Metallische Schmelzen–Reaktionsmedien zur Präparation intermetallischer Verbindungen

MG Kanatzidis, R Pöttgen, W Jeitschko - Angewandte Chemie, 2005 - Wiley Online Library
Ziel dieses Aufsatzes ist es, die Vorzüge von flüssigen Metallen als Lösungsmittel bei der
Synthese intermetallischer und ähnlich zusammengesetzter Verbindungen aufzuzeigen …

Structural, elastic and thermodynamic properties of tetragonal and orthorhombic polymorphs of Sr2GeN2: an ab initio investigation

A Bedjaoui, A Bouhemadou… - High Pressure Research, 2016 - Taylor & Francis
The structural, elastic and thermodynamic properties of the α (tetragonal) and β
(orthorhombic) polymorphs of the Sr2GeN2 compound have been examined in detail using …

Sr (Mg3Ge) N4 and Sr (Mg2Ga2) N4: New isostructural Mg-containing quaternary nitrides with nitridometallate anions of [(Mg3Ge) N4] 2−∞ 3 and [(Mg2Ga2) N4] 2−∞ …

DG Park, Y Dong, FJ DiSalvo - Solid state sciences, 2008 - Elsevier
Two new isostructural Mg-containing quaternary nitrides, Sr (Mg3Ge) N4 and Sr (Mg2Ga2)
N4, were obtained as single crystals from their constituent elements in molten Na. Sr …