Monoterpenoid indole alkaloids are the major class of tryptamine‐derived alkaloids found in
nature. Together with their structural complexity, this has attracted great interest from …

The review summarizes the most recent achievements in the chemistry of 2‐vinylindoles and
3‐vinylindoles. In particular, we focus on the behavior of these compounds as dienes in …

A Ni (NTf2) 2 and tetradentate bisimino-bisquinoline ligand complex catalyzed the
enantioselective Nazarov cyclization of heteroaryl vinyl ketones. An X-ray-quality crystal was …

The catalytic and enantioselective total synthesis of (−)-minovincine has been
accomplished. The key highly substituted hydrocarbazole derivative was obtained by an …

This study analyzes the feasibility of utilizing the catalytic and enantioselective [4+ 2]
cycloaddition of sterically demanding heterocycle-incorporated siloxydienes to yield …

Diels‐Alder reaction is one of the most well‐known named reactions in organic chemistry. It
involves a diene substrate and a dienophile substrate. Among dienes, siloxydiene is a …

A highly efficient catalytic asymmetric [4+ 2] cycloaddition of silyloxyvinylindoles with β, γ-
unsaturated α-ketoesters has been accomplished by an available chiral N, N …

Total syntheses of carbazomycins A and B were demonstrated using a ytterbium-catalyzed
Diels–Alder reaction with (silyloxyvinyl) indole as a diene. The densely substituted benzene …

Lanthanide triflates and a series of hexadentate chiral ligand complexes were synthesized.
X‐ray‐quality crystals were obtained from mixtures of the lanthanide complexes, which were …

RH2 (OAc) 4‐catalyzed coupling of α‐diazo‐γ‐butyrolactams with a wide range of aliphatic
and aromatic thiols leads to α‐aryl (alkyl) thiolactams in generally good yields. The …