Properties and promise of catenated nitrogen systems as high-energy-density materials

OT O'Sullivan, MJ Zdilla - Chemical reviews, 2020 - ACS Publications
The properties of catenated nitrogen molecules, molecules containing internal chains of
bonded nitrogen atoms, is of fundamental scientific interest in chemical structure and …

Sensitivity and performance of energetic materials

S Zeman, M Jungová - Propellants, Explosives, Pyrotechnics, 2016 - Wiley Online Library
This paper provides an overview of the main developments over the past nine years in the
study of the sensitivity of energetic materials (EM) to impact, shock, friction, electric spark …

High performance, low sensitivity: conflicting or compatible?

P Politzer, JS Murray - Propellants, Explosives, Pyrotechnics, 2016 - Wiley Online Library
Some general guidelines and specific molecular/crystalline features for promoting a high
level of detonation performance in conjunction with low sensitivity are proposed. A key point …

Nitrotetrazolate-2N-oxides and the Strategy of N-Oxide Introduction

M Göbel, K Karaghiosoff, TM Klapötke… - Journal of the …, 2010 - ACS Publications
The first anionic tetrazole-2 N-oxide has been prepared by mild aqueous oxidation of easily
prepared 5-nitrotetrazole with commercially available oxone in high yields. The result of …

[PDF][PDF] Some perspectives on estimating detonation properties of C, H, N, O compounds

P Politzer, JS Murray - Central European Journal of Energetic …, 2011 - bibliotekanauki.pl
We have explored various aspects of the Kamlet-Jacobs equations for estimating detonation
velocities and pressures. While the loading density of the explosive compound is certainly …

Nitrogen‐rich bis‐1, 2, 4‐triazoles—a comparative study of structural and energetic properties

AA Dippold, TM Klapötke - Chemistry–A European Journal, 2012 - Wiley Online Library
In this contribution, the synthesis and full structural and spectroscopic characterization of five
bis‐1, 2, 4‐triazoles in combination with different energetic moieties like amino, nitro …

Development and testing of energetic materials: the concept of high densities based on the trinitroethyl functionality

M Göbel, TM Klapötke - Advanced Functional Materials, 2009 - Wiley Online Library
The development of new energetic materials is an emerging area of materials chemistry
facilitated by a worldwide need to replace materials used at present, due to environmental …

Some molecular/crystalline factors that affect the sensitivities of energetic materials: molecular surface electrostatic potentials, lattice free space and maximum heat of …

P Politzer, JS Murray - Journal of molecular modeling, 2015 - Springer
We discuss three molecular/crystalline properties that we believe to be among the factors
that influence the impact/shock sensitivities of energetic materials (ie, their vulnerabilities to …

5, 5′‐Bis (2, 4, 6‐trinitrophenyl)‐2, 2′‐bi (1, 3, 4‐oxadiazole)(TKX‐55): Thermally Stable Explosive with Outstanding Properties

TM Klapötke, TG Witkowski - ChemPlusChem, 2016 - Wiley Online Library
The novel, thermally stable explosive 5, 5′‐bis (2, 4, 6‐trinitro‐phenyl)‐2, 2′‐bi (1, 3, 4‐
oxadiazole)(TKX‐55) is reported. This compound can be prepared by means of a facile …

1, 5-Diaminotetrazole-4 N-oxide (SYX-9): a new high-performing energetic material with a calculated detonation velocity over 10 km s− 1

SR Yocca, M Zeller, EFC Byrd… - Journal of Materials …, 2022 - pubs.rsc.org
5-Amino-1-benzyloxytetrazole was aminated with O-tosylhydroxylamine. The
diaminobenzyloxytetrazolium intermediate was debenzylated to yield the highly energetic 1 …