Readily accessible and shelf-stable 1, 2, 3-triazole and its analogues such as pyridotriazole,
triazoloindole, benzotriazole, and thiadiazole exist in equilibrium with their ring-opened …

The C− N bond is one of the most abundant chemical bonds and widely exists in many
organic molecules and biomacromolecules. The formation and transformation of C− N …

Over the past few years, the development of efficient methods to construct high‐valued N‐
heterocyclic molecules have received massive attention owing to their extensive application …

Metal-stabilized carbenes derived from diazo compounds have become broadly useful
reactive intermediates for organic synthesis. This tutorial review will describe the recent …

Copper-catalyzed azide–alkyne cycloaddition (CuAAC) is a widely utilized, reliable, and
straightforward way for making covalent connections between building blocks containing …

Metal carbenes usually possess versatile reactivities that are controlled by the presence of
both the metals and the ligands. Diazo compounds are commonly used for the generation of …

The area of direct asymmetric functionalization of inert C–H bonds has attracted
considerable attention in recent years. To realize this type of challenging but promising …

Herein we report the synthesis of pyrroloindolines via a catalytic enantioselective formal [3+
2] cycloaddition of C (3)-substituted indoles. This methodology utilizes 4-aryl-1-sulfonyl-1, 2 …

Terminal alkenes are readily available functional groups which appear in α‐olefins
produced by the chemical industry, and they appear in the products of many contemporary …

In recent years, α‐imino rhodium carbene complexes derived by ring‐opening of N‐sulfonyl‐
1, 2, 3‐triazoles have attracted much attention from organic chemists. Many transformations …