Allenylidene and higher cumulenylidene complexes
V Cadierno, J Gimeno - Chemical reviews, 2009 - ACS Publications
Although the free allenylidene species: CdCdCH2 was originally identified in 1961 (trapped
in cold matrixes), 1 it is 1976 when the isolation of the first allenylidene complexes [M …
in cold matrixes), 1 it is 1976 when the isolation of the first allenylidene complexes [M …
Rhodium (I) and iridium (I) complexes with bidentate N, N and P, N ligands as catalysts for the hydrothiolation of alkynes
S Burling, LD Field, BA Messerle, KQ Vuong… - Dalton …, 2003 - pubs.rsc.org
Cationic iridium (I), rhodium (I) complexes containing bis (1-methylimidazol-2-yl) methane,
bim,[M (bim)(CO) 2] BPh4 (M= Ir (1), Rh (2)); bis (pyrazol-1-yl) methane, bpm,[M (bpm)(CO) …
bim,[M (bim)(CO) 2] BPh4 (M= Ir (1), Rh (2)); bis (pyrazol-1-yl) methane, bpm,[M (bpm)(CO) …
New insight into the reactivity of pyridine-functionalized phosphine complexes of ruthenium (II) with respect to olefin metathesis and transfer hydrogenation
E Mothes, S Sentets, MA Luquin, R Mathieu… - …, 2008 - ACS Publications
The present paper deals with the synthesis and full characterization of a series of pyridine-
functionalized phosphine complexes of Ru (II), namely, RuCl2 (Lnx)(PPh3)(Lnx= R2PCH2 …
functionalized phosphine complexes of Ru (II), namely, RuCl2 (Lnx)(PPh3)(Lnx= R2PCH2 …
Synthesis and characterisation of new pyrazole–phosphinite ligands and their ruthenium (II) arene complexes
R Tribó, S Muñoz, J Pons, R Yáñez… - Journal of …, 2005 - Elsevier
The new potentially bidentate pyrazole–phosphinite ligands [(3, 5-dimethyl-1H-pyrazol-1-yl)
methyl diphenylphosphinite](L1) and [2-(3, 5-dimethyl-1H-pyrazol-1-yl) ethyl …
methyl diphenylphosphinite](L1) and [2-(3, 5-dimethyl-1H-pyrazol-1-yl) ethyl …
Rhodium (I) and Iridium (I) Complexes with Bidentate Phosphine− Pyrazolyl Ligands: Highly Efficient Catalysts for the Hydroamination Reaction
LD Field, BA Messerle, KQ Vuong, P Turner… - …, 2007 - ACS Publications
A range of rhodium (I) and iridium (I) complexes containing bidentate phosphine− pyrazolyl
ligands of general formulas [M (R2PyP)(COD)] BPh4 (R= Me, i Pr, Ph, M= Ir, 3b− 3d and M …
ligands of general formulas [M (R2PyP)(COD)] BPh4 (R= Me, i Pr, Ph, M= Ir, 3b− 3d and M …
Reaction of platinum (II) derivatives with 1-hydroxyalkyl-3, 5-dimethylpyrazole ligands. Cleavage of the N (pz) C (sp3) bond. X-ray crystal structure of cis-[PtCl2 (HL2) …
A Boixassa, J Pons, X Solans, M Font-Bardia… - Inorganica chimica acta, 2003 - Elsevier
The reactions of 1-hydroxymethyl-3, 5-dimethylpyrazole (HL1) and 1-(2-hydroxyethyl)-3, 5-
dimethylpyrazole (HL2) with several platinum starting materials ([PtCl2 (CH3CN) 2], cis-and …
dimethylpyrazole (HL2) with several platinum starting materials ([PtCl2 (CH3CN) 2], cis-and …
Variable Coordination Behavior of New Hybrid Pyrazole Ligand: Synthesis and Characterization of Several ZnII, CdII, HgII, PdII, PtII, and NiII Complexes
M Guerrero, J Pons, T Parella, M Font-Bardia… - Inorganic …, 2009 - ACS Publications
In this paper we describe the synthesis of the new mixed-donor ligand 1, 8-bis (3, 5-dimethyl-
1 H-pyrazol-1-yl)-3, 6-dioxaoctane (L). The complexes [MCl2 (L)](M= ZnII (1), CdII (2), HgII …
1 H-pyrazol-1-yl)-3, 6-dioxaoctane (L). The complexes [MCl2 (L)](M= ZnII (1), CdII (2), HgII …
Reactive indolyl complexes of group 9 metals
JHH Ho, DSC Black, BA Messerle, JK Clegg… - …, 2006 - ACS Publications
A series of novel indolyl− imine ligand precursors have been synthesized. In particular,
bidentate, tridentate, and potentially tetradentate ligands were prepared, each containing …
bidentate, tridentate, and potentially tetradentate ligands were prepared, each containing …
Ruthenium Complexes of Electronically Coupled Cyclopentadienone Ligands–Catalysts for Transformations of Propargyl Alcohols
E Haak - 2007 - Wiley Online Library
A series of donor‐and acceptor‐substituted ruthenium cyclopentadienone complexes were
synthesized and their catalytic activities towards propargyl alcohols focused on amination …
synthesized and their catalytic activities towards propargyl alcohols focused on amination …
Allenylidene iron (II) complexes and their deprotonation, nucleophilic addition reactions, and cathodic protonation toward alkynyl derivatives: A chemical and …
AIF Venâncio, MFC Guedes da Silva, LM Martins… - …, 2005 - ACS Publications
The allenylidene complexes trans-[FeBr (CC CRR ')(depe) 2][Y](R= Me, R '= Ph, 1; R= R '=
Ph, 2; R= R '= Et, 3; depe= Et2PCH2CH2PEt2; Y= BF4, BPh4) were obtained by reaction of …
Ph, 2; R= R '= Et, 3; depe= Et2PCH2CH2PEt2; Y= BF4, BPh4) were obtained by reaction of …