Organocatalysis in inert C–H bond functionalization

Y Qin, L Zhu, S Luo - Chemical reviews, 2017 - ACS Publications
As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …

Organocatalytic reactions enabled by N-heterocyclic carbenes

DM Flanigan, F Romanov-Michailidis, NA White… - Chemical …, 2015 - ACS Publications
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes | Chemical Reviews ACS
ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS Publications …

An overview of N-heterocyclic carbenes

MN Hopkinson, C Richter, M Schedler, F Glorius - Nature, 2014 - nature.com
The successful isolation and characterization of an N-heterocyclic carbene in 1991 opened
up a new class of organic compounds for investigation. From these beginnings as academic …

Cobalt-catalyzed nitrogen atom insertion in arylcycloalkenes

J Wang, H Lu, Y He, C Jing, H Wei - Journal of the American …, 2022 - ACS Publications
Developing strategies enabling the modification of underlying molecular frameworks
facilitates access to underexplored chemical spaces. Skeletal editing is an emerging …

A continuing challenge: N-heterocyclic carbene-catalyzed syntheses of γ-butyrolactones

KJR Murauski, AA Jaworski, KA Scheidt - Chemical Society Reviews, 2018 - pubs.rsc.org
Catalytic, stereoselective N-heterocyclic carbene-catalyzed reactions facilitate efficient
construction of many different heterocyclic compounds, such as the enantioenriched 5 …

[HTML][HTML] Carbene and photocatalyst-catalyzed decarboxylative radical coupling of carboxylic acids and acyl imidazoles to form ketones

SC Ren, X Yang, B Mondal, C Mou, W Tian… - Nature …, 2022 - nature.com
The carbene and photocatalyst co-catalyzed radical coupling of acyl electrophile and a
radical precursor is emerging as attractive method for ketone synthesis. However, previous …

[HTML][HTML] Tale of the Breslow intermediate, a central player in N-heterocyclic carbene organocatalysis: then and now

M Pareek, Y Reddi, RB Sunoj - Chemical Science, 2021 - pubs.rsc.org
N-Heterocyclic carbenes (NHCs) belong to the popular family of organocatalysts used in a
wide range of reactions, including that for the synthesis of complex natural products and …

On the mechanism of N-heterocyclic carbene-catalyzed reactions involving acyl azoliums

J Mahatthananchai, JW Bode - Accounts of chemical research, 2014 - ACS Publications
Catalytic reactions promoted by N-heterocyclic carbenes (NHCs) have exploded in
popularity since 2004 when several reports described new fundamental reactions that …

N‐Heterocyclic Carbene Catalysis via Azolium Dienolates: An Efficient Strategy for Remote Enantioselective Functionalizations

XY Chen, Q Liu, P Chauhan… - Angewandte Chemie …, 2018 - Wiley Online Library
N‐heterocyclic carbene (NHC) catalysis has emerged as a powerful strategy in organic
synthesis. In recent years a number of reviews have been published on NHC‐catalyzed …

Recent development of direct asymmetric functionalization of inert C–H bonds

C Zheng, SL You - RSC advances, 2014 - pubs.rsc.org
The area of direct asymmetric functionalization of inert C–H bonds has attracted
considerable attention in recent years. To realize this type of challenging but promising …