Consolidating knowledge from a number of disciplines, Ion-Radical Organic Chemistry:
Principles and Applications, Second Edition presents the recent changes that have occurred …

We recently described the reduction of various tris (substituted cyclopentadienyl) lanthanoid
compounds by potassium metal in the presence of 18-crown-6 (L) in benzene1 or toluene. 2 …

1H NMR studies (400 MHz) on isopropoxycyclooctatetraene (C8H7-O-C3H7) and its ring-d
7 analogue (C8D7-O-C3H7) show that there is an inverse isotope effect on the rate of ring …

B3LYP/6-31+ G* density functional calculations have been performed in order to understand
why large, equilibrium isotope effects have been observed in the reduction of benzene to the …

Abstract DMe-DCNQI-d 7 (DCNQI= dicyanoquiodiimine) was synthesized by applying 1 H/2
D exchange reaction, and its Cu and Li salts were prepared. An extremely sharp metal …

The reaction between small organic molecules and low work function metals is of interest in
organometallic, astronomical, and optoelectronic device chemistry. Here, thin, solid-state …

The sequential addition of deuteriums to the six possiblesites in benzene results in a
nonlinear decrease in the solution EA, and this decrease in the EA is independent of the …

The effect of isotopic substitution on the electron affinity () of benzene and pyrene was
studied using semiempirical MO calculations. Zero-point energy calculations were …

EPR analysis of the anion radicals resulting from the partial potassium reduction of mixtures
of perdeuteriated and perprotiated polyaromatics (* R and R, respectively) in tetrahydrofuran …

Appreciable 14N/15N equilibrium isotope effect has been observed for the electron-transfer
process between N, N, N ', N '-tetramethyl-p-phenylenediamine (TMPD) and its radical …