Enantiomers, where chirality arises from restricted rotation around a single bond, are
atropisomers. Due to the unique nature of the origins of their chirality, synthetic strategies to …

Axially chiral architectures exist widely in natural products, biologically relevant molecules,
chiral ligands and catalysts as well as functional materials. Therefore, catalytic asymmetric …

Catalytic asymmetric dynamic kinetic resolution of configurationally labile bridged biaryls is
emerging as a powerful strategy for atropisomer synthesis. However, the reported examples …

We report an organocatalyst that combines a triazolium N-heterocyclic carbene (NHC) with a
squaramide as a hydrogen-bonding donor (HBD), which can effectively catalyze the …

The development of new methods for regio‐and stereoselective activation of C− O bonds in
ethers holds significant promise for synthetic chemistry, offering advantages in terms of …

Herein, we report an unprecedented strategy for the simultaneous construction of a remote
C–N stereogenic axis and three contiguous stereogenic carbon centers via silver-catalyzed …

We describe herein an intriguing method for the synthesis of biaryl aldehydes bearing both
axial and central chirality through a desymmetric [3+ 2] cycloaddition reaction of activated …

The development of efficient processes for the preparation of structurally diverse axially
chiral biaryls has been an important goal in synthetic organic chemistry and asymmetric …

Atropisomers possessing additional stereogenic centres have found wide applications in
various fields; however, the development of catalytic asymmetric reactions for their …

Axially chiral biaryl scaffolds are important in pharmaceuticals, natural products, and
asymmetric synthesis. Atroposelective ring‐opening of configurationally labile biaryl …