Photophysics of corroles and closely related systems for emergent solar energy, medicinal, and materials science applications

X Zhan, D Kim, Z Ullah, W Lee, Z Gross… - Coordination Chemistry …, 2023 - Elsevier
The scientific research field of corrole systems has witnessed an explosion of interest in
recent years owing to unique optical and electronic properties that are very promising for …

Oxido-molybdenum (V) corroles as robust catalysts for oxidative bromination and selective epoxidation reactions in aqueous media under mild conditions

I Yadav, V Prakash, MR Maurya, M Sankar - Inorganic Chemistry, 2023 - ACS Publications
Two new meso-substituted oxido-molybdenum corroles were synthesized and characterized
by various spectroscopic techniques. In the thermogram, MoO [TTC](1) exhibited excellent …

Recent advances in the functionalization of formyl and acroleyl appended corroles

I Yadav, D Dhiman, M Sankar - Chemical Communications, 2024 - pubs.rsc.org
The field of corrole systems particularly those with functional groups at their peripheral
positions has experienced a surge of interest in recent years, driven by their exceptional …

Synthesis, Spectral, Redox, and Sensing Studies of β-Dicyanovinyl-Appended Corroles and Their Metal Complexes

I Yadav, WR Osterloh, KM Kadish… - Inorganic Chemistry, 2023 - ACS Publications
A new family of β-dicyanovinyl (DCV)-appended corroles represented as MTPC (MN)(where
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …

Push–pull octaphenylporphyrins with mixed substituents pattern: Synthesis, redox, ultrafast dynamics and nonlinear optical studies

S Kumari, I Yadav, JN Acharyya, M Shanu… - Dyes and …, 2023 - Elsevier
A new family of β-functionalized octaphenylporphyrins, MOPP (NO 2) Br 3 (M= 2H, Zn II, Ni II,
or Cu II, and OPP= octaphenylporphyrin) has been synthesized possessing unsymmetrical …

Panchromatic and Perturbed Absorption Spectral Features and Multiredox Properties of Dicyanovinyl-and Dicyanobutadienyl-Appended Cobalt Corroles

I Yadav, M Sankar - Inorganic Chemistry, 2023 - ACS Publications
Four new β-functionalized π-extended cobalt corroles with one and two dicyanovinyl (DCV)
or dicyanobutadienyl (DCBD) moieties at the 3-and 3, 17-positions have been synthesized …

Synthesis of Vanadyl Complexes of N-Confused Porphyrins and Their Bromoperoxidase-like Catalytic Activity

R Kumar, V Prakash, M Sankar - Inorganic Chemistry, 2024 - ACS Publications
Two new vanadyl complexes of N-confused porphyrins (NCPs),[VONCTPP](V-1) and
[VONCP (OMe) 8](V-2), have been synthesized for the first time and investigated as a …

Symmetrically Functionalized Copper and Silver Corrole‐Bis‐Tetracyanobutadiene Push‐Pull Conjugates: Efficient Population of Triplet States via Charge Transfer

I Yadav, JK Sharma, M Sankar… - Chemistry–A European …, 2023 - Wiley Online Library
Copper and silver tritolylcorroles (TTC) are symmetrically functionalized to carry two
tetracyanobutadiene (TCBD) entities via [2+ 2] cycloaddition‐retroeletrocyclization reaction …

Highly Efficient β‐Functionalized Oxidomolybdenum (V) Corroles for Catalytic Oxidative Bromination of Phenols at Room Temperature

I Yadav, V Prakash, RR Kaswan… - European Journal of …, 2023 - Wiley Online Library
Two new β‐functionalized oxidomolybdenum (V) corroles, oxido [3‐formyl‐5, 10, 15‐
triphenylcorrolato] molybdenum (V)(Mo‐1) and oxido [3‐dicyanovinyl‐5, 10, 15 …

Synthesis, Structural, Electrochemical, and DFT Studies of Highly Substituted Nonplanar Ni (II) Porphyrins and Their Intensity-Dependent Third-Order Nonlinear …

AS Bulbul, A Kuriakose, Komal, Reena… - Inorganic …, 2024 - ACS Publications
We designed and successfully synthesized highly substituted electron-deficient nonplanar
Ni (II) porphyrins and their derivatives (1–7) in moderate to good yields. These derivatives …