The bulky, but symmetrically beautiful, adamantane ring system is now pervasive throughout
physical, medicinal and synthetic chemistry, since it was first discovered in 1924 and coined …

The efficient and catalytic amination of unactivated alkenes with simple secondary alkyl
amines is preferentially achieved. A sterically accessible, N, O-chelated cyclic ureate …

The first cationic titanium catalyst system for the intermolecular hydroaminoalkylation of
alkenes with various tertiary alkylamines is presented. Corresponding reactions which …

Intermolecular hydroaminoalkylation reactions of alkynes with secondary amines, which
selectively give access to allylic amines with E configuration of the alkene unit, are achieved …

The reactions of bis (η5: η1-pentafulvene) titanium complexes (1) with 19 different
secondary amines (Aa–s) have been investigated. Depending on the substitution pattern of …

The first examples of titanium‐catalyzed hydroaminoalkylation reactions of ethylene with
secondary amines are presented. The reactions can be achieved with various titanium …

Abstract Sterically demanding 2, 6‐bis (tritylamino) pyridine is used for the synthesis of a
mono (2, 6‐diaminopyridinato) titanium complex that undergoes unexpected intramolecular …

The formation of the titanocene imido complexes 2b, 4, and 5 via double N–H bond
activations at ambient temperature of sterically demanding amines (2, 6-diisopropylaniline …

The regioselective conversion of alkyl‐substituted alkenes into linear hydroaminoalkylation
products represents a strongly desirable synthetic transformation. In particular, such …

Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary
amines take place in the presence of a 2, 6‐bis (phenylamino) pyridinato titanium catalyst …