Vitrimers: Associative dynamic covalent adaptive networks in thermoset polymers
B Krishnakumar, RVSP Sanka, WH Binder… - Chemical Engineering …, 2020 - Elsevier
The vitrimer-thermoset concept represents an important contribution to improve the durability
and recyclability of thermoset-systems. The concept of Associative Dynamic Covalent …
and recyclability of thermoset-systems. The concept of Associative Dynamic Covalent …
Vitrimers: permanent organic networks with glass-like fluidity
W Denissen, JM Winne, FE Du Prez - Chemical science, 2016 - pubs.rsc.org
Most covalent adaptable networks give highly interesting properties for material processing
such as reshaping, recycling and repairing. Classical thermally reversible chemical cross …
such as reshaping, recycling and repairing. Classical thermally reversible chemical cross …
Dynamic covalent chemistry in polymer networks: a mechanistic perspective
JM Winne, L Leibler, FE Du Prez - Polymer Chemistry, 2019 - pubs.rsc.org
The incorporation of dynamic covalent linkages within and between polymer chains brings
new properties to classical thermosetting polymer formulations, in particular in terms of …
new properties to classical thermosetting polymer formulations, in particular in terms of …
Mechanically robust, self-healable, and reprocessable elastomers enabled by dynamic dual cross-links
Y Chen, Z Tang, Y Liu, S Wu, B Guo - Macromolecules, 2019 - ACS Publications
Covalent cross-linking of rubbers is essential for obtaining high resilience and
environmental resistance but prevents healing and recycling. Integrating dynamic covalent …
environmental resistance but prevents healing and recycling. Integrating dynamic covalent …
[HTML][HTML] Recyclable and reformable epoxy resins based on dynamic covalent bonds–Present, past, and future
H Memon, Y Wei, C Zhu - Polymer Testing, 2022 - Elsevier
Epoxy resins, as a typical class of thermosetting polymers, have widespread industrial
applications such as adhesives, coatings, electronic encapsulants, and polymer matrices for …
applications such as adhesives, coatings, electronic encapsulants, and polymer matrices for …
Linear viscoelasticity and flow of self-assembled vitrimers: the case of a polyethylene/dioxaborolane system
RG Ricarte, F Tournilhac, M Cloître, L Leibler - Macromolecules, 2020 - ACS Publications
For vitrimer systems obtained by dynamic cross-linking of polymer chains, incompatibility
effects between the cross-links and polymer backbone can lead to microphase separation …
effects between the cross-links and polymer backbone can lead to microphase separation …
Phase separation and self-assembly in vitrimers: Hierarchical morphology of molten and semicrystalline polyethylene/dioxaborolane maleimide systems
RG Ricarte, F Tournilhac, L Leibler - Macromolecules, 2018 - ACS Publications
Vitrimers are a class of polymers that flow when heated but are insoluble. Vitrimers are
made of covalent networks with dynamic links and/or cross-links that undergo an associative …
made of covalent networks with dynamic links and/or cross-links that undergo an associative …
Unentangled vitrimer melts: interplay between chain relaxation and cross-link exchange controls linear rheology
RG Ricarte, S Shanbhag - Macromolecules, 2021 - ACS Publications
Vitrimers are polymer networks that engage in dynamic associative exchange reactions.
Their covalent cross-links preserve network connectivity but permit topology fluctuations …
Their covalent cross-links preserve network connectivity but permit topology fluctuations …
Vitrimer-assisted construction of boron nitride vertically aligned nacre-mimetic composites for highly thermally conductive thermal interface materials
Modern electronic equipment with high integration and power consumption levels urges for
more effective thermal interface materials (TIMs) to tackle its increasingly severe cooling …
more effective thermal interface materials (TIMs) to tackle its increasingly severe cooling …
Polydimethylsiloxane quenchable vitrimers
T Stukenbroeker, W Wang, JM Winne, FE Du Prez… - Polymer …, 2017 - pubs.rsc.org
An elastomeric vitrimer material was synthesized via the crosslinking of a
polydimethylsiloxane bearing pendant amino functions with a bis-vinylogous urethane …
polydimethylsiloxane bearing pendant amino functions with a bis-vinylogous urethane …