Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

The reaction takes place at a specialized metal center that dramatically increases the acidity
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …

Abstract The [FeFe]-and [NiFe]-hydrogenases catalyze the formal interconversion between
hydrogen and protons and electrons, possess characteristic non-protein ligands at their …

Electroanalytical chemists and others are concerned not only with the application of new
and classical techniques to analytical problems, but also with the fundamental theoretical …

Catalysis enables many aspects of modern life, including fuels, products, plastics, and
medicines. Recent advances in catalysis have enabled us to realize higher efficiencies and …

We describe as 'reversible'a bidirectional catalyst that allows a reaction to proceed at a
significant rate in response to even a small departure from equilibrium, resulting in fast and …

This Article describes the electron transfer (ET) kinetics in complexes of CdS nanorods (CdS
NRs) and [FeFe]-hydrogenase I from Clostridium acetobutylicum (CaI). In the presence of an …

Pathogenic microorganisms use various mechanisms to conserve energy in host tissues
and environmental reservoirs. One widespread but often overlooked means of energy …

Conspectus Redox active metalloenzymes play a major role in energy transformation
reactions in biological systems. Examples include formate dehydrogenases, nitrogenases …

[FeFe] hydrogenases, metalloenzymes catalyzing proton/dihydrogen interconversion, have
attracted intense attention due to their remarkable catalytic properties and (bio-) …