Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …

Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …

Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …

Complete-active-space self-consistent field and N-electron valence second-order
perturbation theory have both been employed to investigate the magnetic anisotropy of one …

Four pentacoordinate complexes, 1–4, of the type [Co (L1) X2] and [Co (L2) X2](where L1=
2, 6-bis (1-octyl-1H-benzimidazol-2-yl) pyridine for 1 and 2, L2= 2, 6-bis (1-dodecyl-1H …

A rational approach of modulating the easy-plane magnetic anisotropy of mononuclear
pentagonal bipyramidal CoII single molecule magnets (SMMs) has been revealed in this …

In this work, the effects of ligand field strength as well as the metal coordination geometry on
magnetic anisotropy of pentacoordinated CoII complexes have been investigated using a …

A tetranuclear cubane-type complex [Co4 (ntfa) 4 (CH3O) 4 (CH3OH) 4](1) with a {Co4O4}
core, and a mononuclear complex [Co (ntfa) 2 (CH3OH) 2](2) have been rationally obtained …

Coordination complexes that possess large magnetic anisotropy (otherwise known as zero-
field splitting, ZFS) have possible applications in the field of magnetic materials, including …

Two isomeric Co (II) complexes with the same general molecular formula of [Co (napy) 2
(NO3) 2](napy= 1, 8-naphthyridine) have been synthesized. X-ray single crystal structural …