Understanding the unceasing evolution of Co (II) based single-ion magnets
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …
Single ion magnets from 3d to 5f: developments and strategies
M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
Largely enhancing the blocking energy barrier and temperature of a linear cobalt (II) complex through the structural distortion: a theoretical exploration
F Lu, WX Guo, YQ Zhang - Inorganic Chemistry, 2021 - ACS Publications
Complete-active-space self-consistent field and N-electron valence second-order
perturbation theory have both been employed to investigate the magnetic anisotropy of one …
perturbation theory have both been employed to investigate the magnetic anisotropy of one …
Pentacoordinate cobalt (II) single ion magnets with pendant alkyl chains: shall we go for chloride or bromide?
J Juráková, JD Midlíková, J Hrubý, A Kliuikov… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Four pentacoordinate complexes, 1–4, of the type [Co (L1) X2] and [Co (L2) X2](where L1=
2, 6-bis (1-octyl-1H-benzimidazol-2-yl) pyridine for 1 and 2, L2= 2, 6-bis (1-dodecyl-1H …
2, 6-bis (1-octyl-1H-benzimidazol-2-yl) pyridine for 1 and 2, L2= 2, 6-bis (1-dodecyl-1H …
Influence of the coordination environment on easy-plane magnetic anisotropy of pentagonal bipyramidal cobalt (II) complexes
A rational approach of modulating the easy-plane magnetic anisotropy of mononuclear
pentagonal bipyramidal CoII single molecule magnets (SMMs) has been revealed in this …
pentagonal bipyramidal CoII single molecule magnets (SMMs) has been revealed in this …
Probing the effects of ligand field and coordination geometry on magnetic anisotropy of pentacoordinate Cobalt (II) single-ion magnets
In this work, the effects of ligand field strength as well as the metal coordination geometry on
magnetic anisotropy of pentacoordinated CoII complexes have been investigated using a …
magnetic anisotropy of pentacoordinated CoII complexes have been investigated using a …
Switching of easy-axis to easy-plane anisotropy in cobalt (II) complexes
Y Wu, J Xi, T Xiao, J Ferrando-Soria… - Inorganic Chemistry …, 2021 - pubs.rsc.org
A tetranuclear cubane-type complex [Co4 (ntfa) 4 (CH3O) 4 (CH3OH) 4](1) with a {Co4O4}
core, and a mononuclear complex [Co (ntfa) 2 (CH3OH) 2](2) have been rationally obtained …
core, and a mononuclear complex [Co (ntfa) 2 (CH3OH) 2](2) have been rationally obtained …
Probing the Magnetic Anisotropy of Co (II) Complexes Featuring Redox-Active Ligands
P Kumar, DJ SantaLucia… - Inorganic …, 2020 - ACS Publications
Coordination complexes that possess large magnetic anisotropy (otherwise known as zero-
field splitting, ZFS) have possible applications in the field of magnetic materials, including …
field splitting, ZFS) have possible applications in the field of magnetic materials, including …
Magnetic properties of two coordination isomeric cobalt (II) single-ion magnets
HH Cui, HJ Xu, T Zhang, S Luo, W Tong, M Wang… - Dalton …, 2023 - pubs.rsc.org
Two isomeric Co (II) complexes with the same general molecular formula of [Co (napy) 2
(NO3) 2](napy= 1, 8-naphthyridine) have been synthesized. X-ray single crystal structural …
(NO3) 2](napy= 1, 8-naphthyridine) have been synthesized. X-ray single crystal structural …