New trends in oxidative functionalization of carbon–hydrogen bonds: A review

GB Shul'pin - Catalysts, 2016 - mdpi.com
This review describes new reactions catalyzed by recently discovered types of metal
complexes and catalytic systems (catalyst+ co-catalyst). Works of recent years (mainly 2010 …

Homo-and heterometallic polynuclear transition metal catalysts for alkane CH bonds oxidative functionalization: Recent advances

DS Nesterov, OV Nesterova, AJL Pombeiro - Coordination Chemistry …, 2018 - Elsevier
Polynuclear homo-and heterometallic complexes of transition metals constitute a broad
class of coordination compounds with recognized applications in catalysis, and polymetallic …

Tris (pyrazol-1-yl) methane metal complexes for catalytic mild oxidative functionalizations of alkanes, alkenes and ketones

LM Martins, AJL Pombeiro - Coordination Chemistry Reviews, 2014 - Elsevier
This work concerns recent advances (since 2005) in the oxidative functionalization of
alkanes, alkenes and ketones, under mild conditions, catalyzed by homoscorpionate tris …

Selectivity enhancement in functionalization of C–H bonds: A review

GB Shul'pin - Organic & biomolecular chemistry, 2010 - pubs.rsc.org
The selectivity is an extremely important characteristic of a chemical reaction. This review
deals mainly with supramolecular and nano-chemical approaches to the problem of …

C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity

GB Shul'pin - Dalton Transactions, 2013 - pubs.rsc.org
This brief essay consists of a few “exciting stories” devoted to relations within a metal-
complex catalyst between a metal ion and a coordinated ligand. When, as in the case of a …

Pyrazinecarboxylic acid and analogs: Highly efficient co-catalysts in the metal-complex-catalyzed oxidation of organic compounds

AM Kirillov, GB Shul'pin - Coordination Chemistry Reviews, 2013 - Elsevier
The development of new metal complex catalysts and efficient protocols for the mild and
selective oxidation of alkanes, arenes, olefins, alcohols, and other organic substrates is a …

Heterometallic CoIII4FeIII2 Schiff Base Complex: Structure, Electron Paramagnetic Resonance, and Alkane Oxidation Catalytic Activity

DS Nesterov, EN Chygorin, VN Kokozay… - Inorganic …, 2012 - ACS Publications
The heterometallic complex [Co4Fe2OSae8]· 4DMF· H2O (1) was synthesized by one-pot
reaction of cobalt powder with iron chloride in a dimethylformamide solution of salicylidene …

Oxidation of alkanes and alcohols with hydrogen peroxide catalyzed by complex Os3(CO)10(µ‐H)2

GB Shul'pin, YN Kozlov, LS Shul'pina… - Applied …, 2010 - Wiley Online Library
Trinuclear carbonyl hydride cluster, Os3 (CO) 10 (µ‐H) 2, catalyzes oxidation of cyclooctane
to cyclooctyl hydroperoxide by hydrogen peroxide in acetonitrile solution. The …

Regioselective oxidation of nonactivated alkyl C–H groups using highly structured non-heme iron catalysts

L Gomez, M Canta, D Font, I Prat, X Ribas… - The Journal of Organic …, 2013 - ACS Publications
Selective oxidation of alkyl C–H groups constitutes one of the highest challenges in organic
synthesis. In this work, we show that mononuclear iron coordination complexes Λ-[Fe …

Gold nanoparticles supported on carbon materials for cyclohexane oxidation with hydrogen peroxide

SAC Carabineiro, L Martins, M Avalos-Borja… - Applied Catalysis A …, 2013 - Elsevier
Abstract Gold (1 wt.%) was loaded on several types of carbon materials (activated carbon,
polymer based carbon xerogels, multi-walled carbon nanotubes, nanodiamonds …