Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach

C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …

Stimuli-cleavable moiety enabled vinyl polymer degradation and emerging applications

J Zheng, ZM Png, XCN Quek, XJ Loh, Z Li - Green Chemistry, 2023 - pubs.rsc.org
Vinyl polymers have become ubiquitous products in our modern world, thanks to their
exceptional strength, durability, and resistance to chemicals, all of which result from their …

Increasing the hydrophilicity of cyclic ketene acetals improves the hydrolytic degradation of vinyl copolymers and the interaction of glycopolymer nanoparticles with …

T Pesenti, E Gillon, S Ishii, S Messaoudi… - …, 2023 - ACS Publications
Radical ring-opening polymerization (rROP) of cyclic ketene acetals (CKAs) with traditional
vinyl monomers allows the synthesis of degradable vinyl copolymers. However, since the …

Plenty of Space in the Backbone: Radical Ring‐Opening Polymerization

F Sbordone, H Frisch - Chemistry–A European Journal, 2024 - Wiley Online Library
Radical polymerization is the most widely applied technique in both industry and
fundamental science. However, its major drawback is that it typically yields polymers with …

Biodegradable mPEG-b-poly (MDO-co-vinyl esters) block copolymers as a viable nanocarrier platform with tuneable disassembly

A Balaji, AR Prior, RK O'Reilly, AP Dove… - Polymer …, 2024 - pubs.rsc.org
Xanthate-based copolymerisations of 2-methylene-1, 3-dioxepane (MDO) and vinyl acetate-
derivative monomers were conducted using a versatile mPEG macroCTA to create …

Ring-Opening Polymerization of Representative Carbocyclic and Oxacyclic Monomers: Versatile Platform toward Advanced Functional Polymers

Y He, Z Li, D Zhao, Y Shen, W Fu, Z Li - Progress in Polymer Science, 2024 - Elsevier
Ring-opening polymerization (ROP) has emerged as a significant method in polymer
synthesis, with a focus on designing and creating diverse cyclic monomers that enhance …

Radical ring-opening polymerization towards degradable polymer as chain extender for polylactic acid

XY Gu, WJ Wu, XL Sun, H Deng, QH Chen - Polymer, 2024 - Elsevier
Degradable polymer materials have gained considerable research efforts nowadays.
However, widely utilized polymeric chain extenders for degradable polymer materials are …

Degradable Underwater Adhesive Utilizing Free Radical Ring-Opening Polymerization

J Ding, Y Han, J Wu, D Chen, C Xiong… - ACS Applied Polymer …, 2024 - ACS Publications
Inspired by the amino acid residues in mussel adhesion proteins, vinyl polymer underwater
adhesives containing dopamine structures have gradually become a research hot spot …

LA COPOLYMERISATION RADICALAIRE PAR OUVERTURE DE CYCLE DES ACETALS DE CETENE CYCLIQUES: UNE NOUVELLE VOIE D'ACCES POUR LA …

T PESENTI - JOURNÉE NOUVEAUX ENTRANTS - universite-paris-saclay.fr
Les polymères vinyliques représentent plus de la moitié des polymères synthétisés en
Europe, notamment à travers les plastiques. 1 En effet, leur grande résistance chimique et …