Strategies for designing metal–organic frameworks with superprotonic conductivity

A Sharma, J Lim, MS Lah - Coordination Chemistry Reviews, 2023 - Elsevier
The use of metal ions and organic linkers to generate metal–organic frameworks (MOFs)
with various functionalities, porosity, and dimensionality has attracted the attention of …

Switched Proton Conduction in Metal–Organic Frameworks

F Xiang, S Chen, Z Yuan, L Li, Z Fan, Z Yao, C Liu… - JACS Au, 2022 - ACS Publications
Stimuli-responsive materials can respond to external effects, and proton transport is
widespread and plays a key role in living systems, making stimuli-responsive proton …

A cage-on-MOF strategy to coordinatively functionalize mesoporous MOFs for manipulating selectivity in adsorption and catalysis

Y Liang, X Yang, X Wang, ZJ Guan, H Xing… - Nature …, 2023 - nature.com
Functionalizing porous materials with capping agents generates hybrid materials with
enhanced properties, while the challenge is how to improve the selectivity and maintain the …

Bio‐Inspired Synthetic Hydrogen‐Bonded Organic Frameworks for Efficient Proton Conduction

Y Sun, J Wei, Z Fu, M Zhang, S Zhao, G Xu… - Advanced …, 2023 - Wiley Online Library
Hydrogen‐bonded organic frameworks (HOFs) are a rising class of promising proton‐
conducting materials. However, they always suffer from the inherent contradiction between …

Ce-mediated molecular tailoring on gigantic polyoxometalate {Mo132} into half-closed {Ce11Mo96} for high proton conduction

XX Li, CH Li, MJ Hou, B Zhu, WC Chen, CY Sun… - Nature …, 2023 - nature.com
Precise synthesis of polyoxometalates (POMs) is important for the fundamental
understanding of the relationship between the structure and function of each building motif …

Boosting catalytic performance of MOF-808 (Zr) by direct generation of rich defective Zr nodes via a solvent-free approach

G Ye, L Wan, Q Zhang, H Liu, J Zhou, L Wu… - Inorganic …, 2023 - ACS Publications
Creation of rich open metal sites (defect) on the nodes of metal–organic frameworks (MOFs)
is an efficient approach to enhance their catalytic performance in heterogeneous reactions; …

Thiosalicylic‐Acid‐Mediated Coordination Structure of Nickel Center via Thermodynamic Modulation for Aqueous Ni–Zn Batteries

Y Su, G Yuan, J Hu, G Zhang, Y Tang… - Advanced …, 2024 - Wiley Online Library
Uniquely functional nanocomplexes with rich coordination environments are critical in
energy storage. However, the construction of structurally versatile nanocomplexes remains …

Sulfamic acid modified UiO-66 metal-organic framework for biodiesel production: Process optimization using response surface methodology, kinetics, and …

SP Gouda, D Shi, S Basumatary, H Li… - Chemical Engineering …, 2024 - Elsevier
A novel sulfamic acid-modified UiO-66 metal–organic framework (UiO-66/SA) catalyst was
synthesized in this work for the esterification of oleic acid to biodiesel. Oleic acid was used …

Construction of biomimetic proton transport channels in metal-organic framework

XM Li, J Jia, D Yang, J Jin, J Gao - Chinese Chemical Letters, 2024 - Elsevier
Construction of proton transport channels in metal-organic frameworks (MOFs) with simple
synthesis processes, high proton conductivities and good performance stabilities has been …

Achieving high intrinsic proton conductivity via functionalization of MOF-808 by ionic liquid

J Jia, XM Li, H Wu, Q Huang, J Gao - ACS Sustainable Chemistry …, 2023 - ACS Publications
Achieving high intrinsic proton conductivity is essential for the development of stable proton
conductors in proton exchange membrane fuel cells. Herein, an ionic liquid (IL) with a …