Gold-catalyzed synthesis of small rings

M Mato, A Franchino, C Garcı́a-Morales… - Chemical …, 2020 - ACS Publications
Three-and four-membered rings, widespread motifs in nature and medicinal chemistry, have
fascinated chemists ever since their discovery. However, due to energetic considerations …

Stereodivergent catalysis

IP Beletskaya, C Najera, M Yus - Chemical reviews, 2018 - ACS Publications
This review covers diastereo-and enantiodivergent catalyzed reactions in acyclic and cyclic
systems using metal complexes or organocatalysts. Among them, nucleophilic addition to …

Gold (I)-catalyzed activation of alkynes for the construction of molecular complexity

R Dorel, AM Echavarren - Chemical reviews, 2015 - ACS Publications
For centuries, gold had been considered a precious, purely decorative inert metal. It was not
until 1986 that Ito and Hayashi described the first application of gold (I) in homogeneous …

Gold catalysis in total synthesis–recent achievements

D Pflästerer, ASK Hashmi - Chemical Society Reviews, 2016 - pubs.rsc.org
Gold catalysis in total synthesis – recent achievements - Chemical Society Reviews (RSC
Publishing) DOI:10.1039/C5CS00721F Royal Society of Chemistry View PDF VersionPrevious …

Divergent strategy in natural product total synthesis

L Li, Z Chen, X Zhang, Y Jia - Chemical reviews, 2018 - ACS Publications
The divergent total syntheses of complex natural products from a common intermediate have
attracted enormous attention in the chemical community in the past few years because it can …

Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox

D Qian, J Zhang - Chemical Society Reviews, 2015 - pubs.rsc.org
Homogeneous gold-catalyzed cyclopropanation has emerged as a powerful method in
organic synthesis due to its rich chemistry and fascinating reactivity. This thriving strategy is …

Cascade polycyclizations in natural product synthesis

R Ardkhean, DFJ Caputo, SM Morrow, H Shi… - Chemical Society …, 2016 - pubs.rsc.org
Cascade (domino) reactions have an unparalleled ability to generate molecular complexity
from relatively simple starting materials; these transformations are particularly appealing …

Recent advances in construction of polycyclic natural product scaffolds via one-pot reactions involving alkyne annulation

L Zheng, R Hua - Frontiers in Chemistry, 2020 - frontiersin.org
Polycyclic scaffolds are omnipresent in natural products and drugs, and the synthetic
strategies and methods toward construction of these scaffolds are of particular importance …

Tricyclic sesquiterpenes from marine origin

F Le Bideau, M Kousara, L Chen, L Wei… - Chemical …, 2017 - ACS Publications
The structure elucidation, biosynthesis, and biological activity of marine carbotricyclic
sesquiterpene compounds are reviewed from the pioneering results to the end of 2015 …

Metal-catalyzed cycloisomerization as a powerful tool in the synthesis of complex sesquiterpenoids

CI Stathakis, PL Gkizis, AL Zografos - Natural product reports, 2016 - pubs.rsc.org
Covering: up to 2015 Sesquiterpenoids are consistently attracting the interest of the scientific
community due to their promising clinical profile as therapeutic agents. Cycloisomerization …