Nonaqueous polar solvents in reverse micelle systems
2. BACKGROUND 2.1. Aqueous Reverse Micelles The unique properties of water including
its polarity and highly structured hydrogen bond network have led to the widespread use of …
its polarity and highly structured hydrogen bond network have led to the widespread use of …
Analysis of water in confined geometries and at interfaces
MD Fayer, NE Levinger - Annual review of analytical chemistry, 2010 - annualreviews.org
The properties of water depend on its extended hydrogen bond network and the continual
picosecond–time scale structural evolution of the network. Water molecules in confined …
picosecond–time scale structural evolution of the network. Water molecules in confined …
Solute-induced retardation of water dynamics probed directly by terahertz spectroscopy
U Heugen, G Schwaab… - Proceedings of the …, 2006 - National Acad Sciences
The dynamics of water surrounding a solute is of fundamental importance in chemistry and
biology. The properties of water molecules near the surface of a bio-molecule have been the …
biology. The properties of water molecules near the surface of a bio-molecule have been the …
Testing the core/shell model of nanoconfined water in reverse micelles using linear and nonlinear IR spectroscopy
IR Piletic, DE Moilanen, DB Spry… - The Journal of …, 2006 - ACS Publications
A core/shell model has often been used to describe water confined to the interior of reverse
micelles. The validity of this model for water encapsulated in AOT/isooctane reverse micelles …
micelles. The validity of this model for water encapsulated in AOT/isooctane reverse micelles …
Hydrogen bond dynamics in aqueous NaBr solutions
Hydrogen bond dynamics of water in NaBr solutions are studied by using ultrafast 2D IR
vibrational echo spectroscopy and polarization-selective IR pump–probe experiments. The …
vibrational echo spectroscopy and polarization-selective IR pump–probe experiments. The …
Ultrafast 2D-IR vibrational echo spectroscopy: a probe of molecular dynamics
Ultrafast two dimensional infrared (2D-IR) vibrational echo spectroscopy has emerged as a
powerful method for the study of molecular dynamics under thermal equilibrium conditions …
powerful method for the study of molecular dynamics under thermal equilibrium conditions …
Confinement or the nature of the interface? Dynamics of nanoscopic water
DE Moilanen, NE Levinger, DB Spry… - Journal of the American …, 2007 - ACS Publications
The dynamics of water confined in two different types of reverse micelles are studied using
ultrafast infrared pump− probe spectroscopy of the hydroxyl OD stretch of HOD in H2O …
ultrafast infrared pump− probe spectroscopy of the hydroxyl OD stretch of HOD in H2O …
Proton transport and the water environment in Nafion fuel cell membranes and AOT reverse micelles
The properties of confined water and diffusive proton-transfer kinetics in the nanoscopic
water channels of Nafion fuel cell membranes at various hydration levels are compared to …
water channels of Nafion fuel cell membranes at various hydration levels are compared to …
Water dynamics in large and small reverse micelles: From two ensembles to collective behavior
DE Moilanen, EE Fenn, D Wong… - The Journal of chemical …, 2009 - pubs.aip.org
The dynamics of water in Aerosol-OT reverse micelles are investigated with ultrafast infrared
spectroscopy of the hydroxyl stretch. In large reverse micelles, the dynamics of water are …
spectroscopy of the hydroxyl stretch. In large reverse micelles, the dynamics of water are …
Structural rearrangements in water viewed through two-dimensional infrared spectroscopy
ST Roberts, K Ramasesha… - Accounts of chemical …, 2009 - ACS Publications
Compared with other molecular liquids, water is highly structured because of its ability to
form up to four hydrogen bonds, resulting in a tetrahedral network of molecules. However …
form up to four hydrogen bonds, resulting in a tetrahedral network of molecules. However …