Frustrated Lewis pair chemistry: development and perspectives
DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …
solution that are deterred from strong adduct formation by steric and/or electronic factors …
Frustrated Lewis pairs: from concept to catalysis
DW Stephan - Accounts of chemical research, 2015 - ACS Publications
Conspectus Frustrated Lewis pair (FLP) chemistry has emerged in the past decade as a
strategy that enables main-group compounds to activate small molecules. This concept is …
strategy that enables main-group compounds to activate small molecules. This concept is …
Frustrated lewis pairs
DW Stephan - Journal of the American Chemical Society, 2015 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …
discovery that H2 can be reversibly activated by combinations of sterically encumbered …
Catalytic hydroboration of carbonyl derivatives, imines, and carbon dioxide
Organoborane compounds present a class of versatile synthetic intermediate for myriad
organic transformations. The direct addition of a B–H bond across unsaturated bond …
organic transformations. The direct addition of a B–H bond across unsaturated bond …
Chemie frustrierter Lewis‐Paare: Entwicklung und Perspektiven
DW Stephan, G Erker - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …
Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides
DW Stephan, G Erker - Chemical Science, 2014 - pubs.rsc.org
Frustrated Lewis pairs have been used to activate a variety of small molecules. In this review
we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP …
we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP …
Boron-mediated activation of carbon dioxide
S Bontemps - Coordination Chemistry Reviews, 2016 - Elsevier
Carbon dioxide is a very abundant molecule that is used as building block by nature. It
would be a sustainable resource for our carbon-based societies if we could emulate nature …
would be a sustainable resource for our carbon-based societies if we could emulate nature …
Reactivity models of hydrogen activation by frustrated Lewis pairs: synergistic electron transfers or polarization by electric field?
Two alternative qualitative reactivity models have recently been proposed to interpret the
facile heterolytic cleavage of H2 by frustrated Lewis pairs (FLPs). Both models assume that …
facile heterolytic cleavage of H2 by frustrated Lewis pairs (FLPs). Both models assume that …
Carbene‐9‐BBN Ring Expansions as a Route to Intramolecular Frustrated Lewis Pairs for CO2 Reduction
T Wang, DW Stephan - Chemistry–A European Journal, 2014 - Wiley Online Library
Reactions of phosphine‐derived carbenes with 9‐borabicyclo [3.3. 1] nonane (9‐BBN) result
in ring‐expansion reactions to generate novel intramolecular frustrated Lewis pairs (FLPs) …
in ring‐expansion reactions to generate novel intramolecular frustrated Lewis pairs (FLPs) …
Donor‐Acceptor Activation of Carbon Dioxide
M Pérez‐Jiménez, H Corona… - … A European Journal, 2023 - Wiley Online Library
The activation and functionalization of carbon dioxide entails great interest related to its
abundance, low toxicity and associated environmental problems. However, the inertness of …
abundance, low toxicity and associated environmental problems. However, the inertness of …