Frustrated Lewis pair chemistry: development and perspectives

DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

Frustrated Lewis pairs: from concept to catalysis

DW Stephan - Accounts of chemical research, 2015 - ACS Publications
Conspectus Frustrated Lewis pair (FLP) chemistry has emerged in the past decade as a
strategy that enables main-group compounds to activate small molecules. This concept is …

Frustrated lewis pairs

DW Stephan - Journal of the American Chemical Society, 2015 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …

Catalytic hydroboration of carbonyl derivatives, imines, and carbon dioxide

CC Chong, R Kinjo - ACS Catalysis, 2015 - ACS Publications
Organoborane compounds present a class of versatile synthetic intermediate for myriad
organic transformations. The direct addition of a B–H bond across unsaturated bond …

Chemie frustrierter Lewis‐Paare: Entwicklung und Perspektiven

DW Stephan, G Erker - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …

Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

DW Stephan, G Erker - Chemical Science, 2014 - pubs.rsc.org
Frustrated Lewis pairs have been used to activate a variety of small molecules. In this review
we focus on the recent chemistry of FLPs with CO2, CO, N2O, NO and SO2. While FLP …

Boron-mediated activation of carbon dioxide

S Bontemps - Coordination Chemistry Reviews, 2016 - Elsevier
Carbon dioxide is a very abundant molecule that is used as building block by nature. It
would be a sustainable resource for our carbon-based societies if we could emulate nature …

Reactivity models of hydrogen activation by frustrated Lewis pairs: synergistic electron transfers or polarization by electric field?

TA Rokob, I Bako, A Stirling, A Hamza… - Journal of the American …, 2013 - ACS Publications
Two alternative qualitative reactivity models have recently been proposed to interpret the
facile heterolytic cleavage of H2 by frustrated Lewis pairs (FLPs). Both models assume that …

Carbene‐9‐BBN Ring Expansions as a Route to Intramolecular Frustrated Lewis Pairs for CO2 Reduction

T Wang, DW Stephan - Chemistry–A European Journal, 2014 - Wiley Online Library
Reactions of phosphine‐derived carbenes with 9‐borabicyclo [3.3. 1] nonane (9‐BBN) result
in ring‐expansion reactions to generate novel intramolecular frustrated Lewis pairs (FLPs) …

Donor‐Acceptor Activation of Carbon Dioxide

M Pérez‐Jiménez, H Corona… - … A European Journal, 2023 - Wiley Online Library
The activation and functionalization of carbon dioxide entails great interest related to its
abundance, low toxicity and associated environmental problems. However, the inertness of …