Oxide–and silicate–water interfaces and their roles in technology and the environment

JL Bañuelos, E Borguet, GE Brown Jr… - Chemical …, 2023 - ACS Publications
Interfacial reactions drive all elemental cycling on Earth and play pivotal roles in human
activities such as agriculture, water purification, energy production and storage …

Enhancing SOFC cathode performance by surface modification through infiltration

D Ding, X Li, SY Lai, K Gerdes, M Liu - Energy & Environmental …, 2014 - pubs.rsc.org
Solid oxide fuel cells (SOFCs) have the potential to be one of the cleanest and most efficient
energy technologies for direct conversion of chemical fuels to electricity. Economically …

The significance of properly reporting turnover frequency in electrocatalysis research

S Anantharaj, PE Karthik, S Noda - … Chemie International Edition, 2021 - Wiley Online Library
For decades, turnover frequency (TOF) has served as an accurate descriptor of the intrinsic
activity of a catalyst, including those in electrocatalytic reactions involving both fuel …

Tuning electrochemically driven surface transformation in atomically flat LaNiO3 thin films for enhanced water electrolysis

C Baeumer, J Li, Q Lu, AYL Liang, L Jin, HP Martins… - Nature materials, 2021 - nature.com
Abstract Structure–activity relationships built on descriptors of bulk and bulk-terminated
surfaces are the basis for the rational design of electrocatalysts. However, electrochemically …

Ambient-pressure XPS study of a Ni–Fe electrocatalyst for the oxygen evolution reaction

H Ali-Löytty, MW Louie, MR Singh, L Li… - The Journal of …, 2016 - ACS Publications
Chemical analysis of solid–liquid interfaces under electrochemical conditions has recently
become feasible due to the development of new synchrotron radiation techniques. Here we …

Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol

JH Kroll, NM Donahue, JL Jimenez, SH Kessler… - Nature …, 2011 - nature.com
A detailed understanding of the sources, transformations and fates of organic species in the
environment is crucial because of the central roles that they play in human health …

Hard x-ray photoelectron spectroscopy: a snapshot of the state-of-the-art in 2020

C Kalha, NK Fernando, P Bhatt… - Journal of Physics …, 2021 - iopscience.iop.org
Hard x-ray photoelectron spectroscopy (HAXPES) is establishing itself as an essential
technique for the characterisation of materials. The number of specialised photoelectron …

Surface science under reaction conditions: CO oxidation on Pt and Pd model catalysts

MA Van Spronsen, JWM Frenken… - Chemical Society …, 2017 - pubs.rsc.org
Platinum and palladium are frequently used as catalytic materials, for example for the
oxidation of CO. This is one of the most widely studied reactions in the field of surface …

Using “tender” X-ray ambient pressure X-ray photoelectron spectroscopy as a direct probe of solid-liquid interface

S Axnanda, EJ Crumlin, B Mao, S Rani, R Chang… - Scientific reports, 2015 - nature.com
We report a new method to probe the solid-liquid interface through the use of a thin liquid
layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of …

Redox activity of surface oxygen anions in oxygen-deficient perovskite oxides during electrochemical reactions

DN Mueller, ML Machala, H Bluhm… - Nature communications, 2015 - nature.com
Surface redox-active centres in transition-metal oxides play a key role in determining the
efficacy of electrocatalysts. The extreme sensitivity of surface redox states to temperatures, to …