The development of reliable water oxidation catalysts (WOCs) is essential for implementing
artificial photosynthesis on a large technological scale. WOC research has evolved into two …

Many metal–organic frameworks (MOFs) incorporate nodes that are small metal oxide
clusters. Some of these MOFs are stable at high temperatures, offering good prospects as …

Abstract Embedding cubane [M4 (OH) 4](M= Ni, Co) clusters within the matrix of metal–
organic frameworks (MOFs) is a strategy to develop materials with unprecedented …

The S2 state of the Oxygen Evolving Complex (OEC) of Photosystem II (PSII) shows high-
spin (HS) and low-spin (LS) EPR signals attributed to distinct structures based on …

Cobalt oxides are recognized as one of the most efficient earth-abundant catalysts for
challenging oxidation chemistry, with substrates ranging from water to organic compounds …

Pendent metals bound to heterocubanes are components of well-known active sites in
enzymes that mediate difficult chemical transformations. Investigations into the specific role …

Heterogeneous catalysts predominate in large-scale and technologically important
processes because of their privileged stability under harsh operating conditions. Despite this …

Despite extensive biochemical, spectroscopic, and computational studies, the mechanism of
biological water oxidation by the oxygen evolving complex (OEC) of Photosystem II remains …

We demonstrate that allosteric effects and redox state changes can be harnessed to create a
switch that selectively and reversibly regulates the coordination chemistry of a single site on …

C–H activation in alkanes poses a major challenge in chemistry due to the inert character of
this bond, manifesting the necessity of improved catalysts. Although various metal–oxo …