Two-dimensional metal-organic framework materials: synthesis, structures, properties and applications

G Chakraborty, IH Park, R Medishetty… - Chemical Reviews, 2021 - ACS Publications
Among the recent developments in metal-organic frameworks (MOFs), porous layered
coordination polymers (CPs) have garnered attention due to their modular nature and …

Mixed metal-metal organic frameworks (MM-MOFs) and their use as efficient photocatalysts for hydrogen evolution from water splitting reactions

R Jaryal, R Kumar, S Khullar - Coordination Chemistry Reviews, 2022 - Elsevier
Sustainable energy is the need of the hour to cater the global energy demands with zero
carbon emissions. Solar energy is the ultimate, clean and renewable form of energy that can …

Locking effect in metal@ MOF with superior stability for highly chemoselective catalysis

Y Zhong, P Liao, J Kang, Q Liu, S Wang… - Journal of the …, 2023 - ACS Publications
Ultrasmall metal nanoparticles (NPs) show high catalytic activity in heterogeneous catalysis
but are prone to reunion and loss during the catalytic process, resulting in low …

Photopolymerization‐Driven Macroscopic Mechanical Motions of a Composite Film Containing a Vinyl Coordination Polymer

ZY Yang, X Sang, D Liu, QY Li, F Lang… - Angewandte Chemie …, 2023 - Wiley Online Library
We report a unique vinyl coordination polymer (CP),[Zn (4‐Fb) 2 (tkpvb)] n (1, 4‐HFb= 4‐
fluorobenzoic acid, tkpvb= 1, 2, 4, 5‐tetrakis (4‐pyridylvinyl) benzene) that undergoes a rare …

Single-crystal-to-single-crystal [2+ 2] photocycloaddition reaction in a photosalient one-Dimensional coordination polymer of Pb (II)

BB Rath, JJ Vittal - Journal of the American Chemical Society, 2020 - ACS Publications
In a remarkable example, we report a one-dimensional coordination polymer (CP) of Pb (II)
showing photosalient (PS) properties triggered by [2+ 2] cycloaddition of olefinic ligands …

Photoresponsive porous materials

W Danowski, T van Leeuwen, WR Browne… - Nanoscale …, 2021 - pubs.rsc.org
Molecular machines, switches, and motors enable control over nanoscale molecular motion
with unprecedented precision in artificial systems. Integration of these compounds into …

Phase Transition‐Promoted Rapid Photomechanical Motions of Single Crystals of a Triene Coordination Polymer

C Cao, XR Xue, QY Li, MJ Zhang… - Angewandte Chemie …, 2023 - Wiley Online Library
Molecular crystals with the ability to transform light energy into macroscopic mechanical
motions are a promising class of materials with potential applications in actuating and …

Mechanical bending and modulation of photoactuation properties in a one-dimensional Pb (II) coordination polymer

BB Rath, JJ Vittal - Chemistry of Materials, 2021 - ACS Publications
With emerging research on stimuli-responsive materials, dynamic crystals are at the forefront
of investigation. However, research on the mechanical properties of coordination polymers …

The use of photocycloaddition reactions to drive mechanical motions resembling humanoid movements

Y Wang, Q Zhang, Q Liu, BF Abrahams… - Angewandte Chemie …, 2024 - Wiley Online Library
With the aim of producing a photomechanical material for incorporation in soft microrobots, a
one‐dimensional diene coordination polymer (CP)[Cd (F‐bpeb)(3‐CBA) 2] n (CP1, F‐bpeb …

Photomechanical motions in organoboron-based phosphorescent molecular crystals driven by a crystal-state [2+ 2] cycloaddition reaction

S Bhandary, M Beliš, AM Kaczmarek… - Journal of the …, 2022 - ACS Publications
Photoluminescent molecular crystals integrated with the ability to transform light energy into
macroscopic mechanical motions are a promising choice of materials for both actuating and …