Organic fluorine as a hydrogen-bond acceptor: recent examples and applications

PA Champagne, J Desroches, JF Paquin - Synthesis, 2015 - thieme-connect.com
For more than three decades, the ability of a fluorine atom involved in a C–F bond to act as a
hydrogen-bond acceptor has been a controversial issue. Throughout the years, more and …

Organic Binary and Ternary Cocrystal Engineering Based on Halogen Bonding Aimed at Room‐Temperature Phosphorescence

A Abe, K Goushi, M Mamada, C Adachi - Advanced Materials, 2024 - Wiley Online Library
Recently, there has been intense interest in pure organic room‐temperature
phosphorescence (ORTP) from cocrystals composed of 1, 4‐diiodotetrafluorobenzene …

Fluorine substitution tunes the nanofiber chirality of supramolecular hydrogels to promote cell adhesion and proliferation

H Lu, Y Zhao, S Qin, Y Zhang, J Liu, J Zhang… - Advanced Fiber …, 2023 - Springer
Fluorine atoms confer desirable biophysical, chemical, and biological properties to
peptides/proteins by participating in various intermolecular interactions with their …

Structural, electrical, ferroelectric and mechanical properties with Hirshfeld surface analysis of novel NLO semiorganic sodium p-nitrophenolate dihydrate piezoelectric …

J Dalal, N Sinha, H Yadav, B Kumar - RSC advances, 2015 - pubs.rsc.org
Novel non-linear sodium para-nitrophenolate dihydrate (SPNPD) single crystals were grown
by the controlled evaporation method. Various functional groups and chemical bonding …

Experimental and theoretical analysis of lp⋯ π intermolecular interactions in derivatives of 1, 2, 4-triazoles

R Shukla, TP Mohan, B Vishalakshi, D Chopra - CrystEngComm, 2014 - pubs.rsc.org
In the present study, we have synthesized and characterized two biologically active 1, 2, 4-
triazole derivatives, a fluoro derivative, namely (E)-3-(4-fluoro-3-phenoxyphenyl)-4-((4 …

A role of intermolecular interaction modulating thermal diffusivity in organosuperelastic and organoferroelastic cocrystals

S Ranjan, R Morioka, M Ryu, J Morikawa… - Chemical …, 2023 - pubs.rsc.org
Although the finding of superelasticity and ferroelasticity in organic crystals has been
serendipitous, an increasing number of organic crystals with such deformation properties …

Quantitative crystal structure analysis of fluorinated porphyrins

R Soman, S Sujatha, C Arunkumar - Journal of Fluorine Chemistry, 2014 - Elsevier
Herein, we report a series of fluorinated porphyrins, 5, 10, 15, 20-tetrakis (2′, 6′-
difluorophenyl) porphyrin, MT (2′, 6′-DFP) P where M= 2H, 1; Co (II)·(MeOH) 2, 2; Cu (II) …

The dynamic interplay between intramolecular and intermolecular interactions in mononuclear manganese (III) SCO complexes

CY Qin, SZ Zhao, HY Wu, YH Li, ZK Wang… - Dalton …, 2021 - pubs.rsc.org
The effect of counter anions on thermally induced manganese (III)-based SCO within the [Mn
(5-F-sal-N-1, 5, 8, 12)] Y family has been investigated. All the complexes are crystallized …

Study of halogen-mediated weak interactions in a series of halogen-substituted azobenzenes

M Karanam, AR Choudhury - Crystal growth & design, 2013 - ACS Publications
The azobenzenes, known for their various importance in the industry, have been chosen as
model compounds to understand the role of weak interactions involving the C–X (X= F, Cl …

Fluorine versus Hydroxyl in Supramolecular Space: Effect of Organic Fluorine in Molecular Conformation, Lattice Cohesive Energies, and Receptor Binding in a …

A Sudheendranath, Sandeep, K Avinash… - Crystal Growth & …, 2023 - ACS Publications
We examine the effect of organic fluorine in the molecular conformation and supramolecular
packing in a series of α-fluoroketones in comparison to the analogous α-hydroxyketones …