Ligand-Controlled Orthogonal Selectivity between δ and γ Positions of Long-Chain Picolinamides
Aliphatic C (sp3)–H bonds are inherently difficult to activate, owing to their inertness and
chemical indistinguishability. This challenge has been overcome mostly by a directing group …
chemical indistinguishability. This challenge has been overcome mostly by a directing group …
Rhodium-Catalyzed Arene Alkenylation: Selectivity and Reaction Mechanism as a Function of In Situ Oxidant Identity
MT Bennett, KA Park, TB Gunnoe - Organometallics, 2024 - ACS Publications
Rhodium catalyzed arene alkenylation reactions with arenes and olefins using dioxygen as
the direct oxidant (eg, ACS Catal. 2020, 10, 11519), Cu (II) carboxylates (eg, Science 2015 …
the direct oxidant (eg, ACS Catal. 2020, 10, 11519), Cu (II) carboxylates (eg, Science 2015 …
Synergistic Palladium/Silver/Ligand Catalysis for C− H Alkenylation of 2, 1, 3‐Benzofused Heterodiazoles
S Jeong, C Lee, JM Joo - Advanced Synthesis & Catalysis, 2024 - Wiley Online Library
The combination of palladium and silver complexes has emerged as a bimetallic catalytic
system in C− H activation, frequently outperforming palladium‐only systems. Beyond the …
system in C− H activation, frequently outperforming palladium‐only systems. Beyond the …