Homogeneous functionalization of methane

NJ Gunsalus, A Koppaka, SH Park, SM Bischof… - Chemical …, 2017 - ACS Publications
One of the remaining “grand challenges” in chemistry is the development of a next
generation, less expensive, cleaner process that can allow the vast reserves of methane …

Chemo-and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes

EP Talsi, KP Bryliakov - Coordination Chemistry Reviews, 2012 - Elsevier
The discovery of simple and efficient catalyst systems for the selective oxofunctionalization
of hydrocarbons is a challenging task of modern chemistry. The biomimetic approach, which …

New trends in oxidative functionalization of carbon–hydrogen bonds: A review

GB Shul'pin - Catalysts, 2016 - mdpi.com
This review describes new reactions catalyzed by recently discovered types of metal
complexes and catalytic systems (catalyst+ co-catalyst). Works of recent years (mainly 2010 …

Selectivity enhancement in functionalization of C–H bonds: A review

GB Shul'pin - Organic & biomolecular chemistry, 2010 - pubs.rsc.org
The selectivity is an extremely important characteristic of a chemical reaction. This review
deals mainly with supramolecular and nano-chemical approaches to the problem of …

Hydrocarbon oxygenations with peroxides catalyzed by metal compounds

GB Shul'pin - Mini-Reviews in Organic Chemistry, 2009 - ingentaconnect.com
Recent works devoted to the oxygenations of saturated, aromatic as well as olefinic
hydrocarbons are surveyed, and the emphasis is made on the author's own publications …

C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity

GB Shul'pin - Dalton Transactions, 2013 - pubs.rsc.org
This brief essay consists of a few “exciting stories” devoted to relations within a metal-
complex catalyst between a metal ion and a coordinated ligand. When, as in the case of a …

Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes

RV Ottenbacher, DG Samsonenko, EP Talsi… - Organic …, 2012 - ACS Publications
Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with
H2O2, Catalyzed by Aminopyridine Manganese Complexes | Organic Letters ACS ACS …

Highly Enantioselective C−H Oxidation of Arylalkanes with H2O2 in the Presence of Chiral Mn‐Aminopyridine Complexes

EP Talsi, DG Samsonenko, RV Ottenbacher… - …, 2017 - Wiley Online Library
Bioinspired chiral Mn‐aminopyridine complexes [(S, S)‐LMnII (OTf) 2] and [(R, R)‐LMnII
(OTf) 2](where (S, S)‐L=(2S, 2′ S)‐1, 1′‐bis ((3‐methyl‐4‐(2, 2, 2‐trifluoroethoxy) pyridin …

A hydroperoxo-rebound mechanism of alkane oxidation with hydrogen peroxide catalyzed by binuclear manganese (IV) complex in the presence of an acid with …

GB Shul'pin, DS Nesterov, LS Shul'pina… - Inorganica Chimica …, 2017 - Elsevier
The binuclear manganese (IV) complex [Mn 2 L 2 O 3][PF 6] 2 (L= 1, 4, 7-trimethyl-1, 4, 7-
triazacyclononane)(compound 1) catalyzes very efficiently the oxygenation of alkanes with H …

Efficient Epoxidation of Electron‐Deficient Alkenes with Hydrogen Peroxide Catalyzed by [γ‐PW10O38V2(μ‐OH)2]3−

K Kamata, K Sugahara, K Yonehara… - … A European Journal, 2011 - Wiley Online Library
A divanadium‐substituted phosphotungstate,[γ‐PW10O38V2 (μ‐OH) 2] 3−(I), showed the
highest catalytic activity for the H2O2‐based epoxidation of allyl acetate among vanadium …