One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

In this tutorial review taking X-ray crystallographically characterized compounds as a starting
point a walk is taken through the electronic and structural properties of endohedral …

A key characteristic of the element cerium is its reversible redox chemistry between trivalent
and tetravalent forms, which is central to the application of cerium in synthetic and materials …

Clusterfullerenes represent a novel branch of endohedral fullerenes, which are
characterized by a robust fullerene cage with metal clusters encaged in its hollow. Since the …

Titanium/yttrium mixed metal nitride clusterfullerene (MMNCF) TiY2N@ C80 has been
successfully synthesized, representing the first Ti-containing non-scandium MMNCF …

Revealing the transformation routes among existing fullerene isomers is key to
understanding the formation mechanism of fullerenes which is still unclear now because of …

The clusterfullerene Sc4O2@ C80 with a mixed redox state of scandium was found to be an
exciting molecule for endohedral electrochemistry as demonstrated by means of an in situ …

Carbide clusterfullerene DyYTiC@ C80-Ih with three different metal atoms in the endohedral
cluster is obtained by arc-discharge synthesis with methane as reactive gas and is …