Conspectus The variability of chemical bonding in open-shell transition-metal complexes not
only motivates their study as functional materials and catalysts but also challenges …

Phosphorus mononitride (PN) only has a fleeting existence on Earth, and molecular
precursors for the release of this molecule under mild conditions in solution have remained …

Reaction of the ruthenium carbene complex Cp*(IPr) RuCl (1)(IPr= 1, 3-bis (Dipp) imidazol-2-
ylidene; Dipp= 2, 6-diisopropylphenyl) with sodium phosphaethynolate (NaOCP) led to …

Iron-sulfur clusters are critical to a plethora of biological processes; however, little is known
about the elementary unit of these clusters, namely, the [Fe= S] n+ fragment. Here, we report …

The interstellar candidate phosphorus mononitride PN, a metastable species, was
generated through high‐vacuum flash pyrolysis of (o‐phenyldioxyl) phosphinoazide in …

In contrast to its lighter congener N 2, neutral diphosphorus with a P≡ P triple bond is a
highly reactive species observable only in the gas phase and by matrix isolation. Previous …

Herein, we report the synthesis of carbene-stabilized 1, 3-diaza-2, 4-diphosphabutenes
CAACMePNPNCAACMe 4 CAAC (CAACMe= 1-[2, 6-bis (isopropyl) phenyl]-3, 3, 5, 5 …

We expand upon the synthetic utility of anionic rhenium complex Na [(BDI) ReCp](1, BDI= N,
N'-bis (2, 6-diisopropylphenyl)-3, 5-dimethyl-β-diketiminate) to generate several rhenium …

11-Azido-9, 10-dihydro-9, 10-phosphanoanthracene (N3P A) has been demonstrated
recently as a transfer reagent for molecular phosphorus mononitride (PN) because it easily …

Herein, we report the synthesis of an acyclic carbene-stabilized diphospha (aminyl) PNP
radical CAACMePNPCAACMe 4 (CAACMe= 1-[2, 6-bis (isopropyl) phenyl]-3, 3, 5, 5 …