Chemoenzymatic dynamic kinetic resolution (DKR) constitutes a convenient and efficient
method to access enantiomerically pure alcohol and amine derivatives. This Perspective …

Stereoconvergent catalysis is an important subset of asymmetric synthesis that
encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic …

The alkylation of amines by alcohols has been achieved using 0.5 mol%[Ru (p-cymene) Cl2]
2 with the bidentate phosphines dppf or DPEphos as the catalyst. Primary amines have …

Biocatalysis has become an important tool in chemical synthesis, allowing access to
complex molecules with high levels of activity and selectivity and with low environmental …

Asymmetric metal based catalysis has advanced quickly in recent years, with its efficiency
relying exclusively on chiral ligands. Rational design and meticulous selection of chiral …

Optically active amines and amino acids play an important role in the pharmaceutical,
agrochemical, and chemical industries. They are frequently used as synthons for the …

This review updates the principal methods used to obtain dynamic kinetic resolution (DKR)
by either enzymatic or nonenzymatic methods, covering the literature from 2008 to the …

Allylic alcohols represent an important and highly versatile class of chiral building blocks for
organic synthesis. This Review summarizes the plethora of methods developed for the …

Dynamic kinetic resolutions have proven to be a useful method for the preparation of
enantiopure compounds from racemates, leading to the formation of a single enantiomer in …

In a continuous effort to emulate the efficiency of biosynthetic pathways, considerable
progress has been made in developing one-pot chemoenzymatic processes that take full …