Yet another perspective on hole interactions

N Tarannam, R Shukla, S Kozuch - Physical Chemistry Chemical …, 2021 - pubs.rsc.org
Hole interactions are known by different names depending on the key atom of the bond
(halogen bond, chalcogen bond, hydrogen bond, etc.), and the geometry of the interaction (σ …

Spodium bonds: noncovalent interactions involving group 12 elements

A Bauzá, I Alkorta, J Elguero… - Angewandte Chemie …, 2020 - Wiley Online Library
The term spodium (Sp) bond is proposed to refer to a net attractive interaction between any
element of Group 12 and electron‐rich atoms (Lewis bases or anions). These noncovalent …

Unified classification of non-covalent bonds formed by main group elements: a bridge to chemical bonding

A Das, E Arunan - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Using correlation plots of binding energy and electron density at the bond critical point, we
investigated the nature of intermolecular non-covalent bonds (D–X⋯ A, where D …

Differentiating intramolecular spodium bonds from coordination bonds in two polynuclear zinc (II) Schiff base complexes

T Basak, RM Gomila, A Frontera, S Chattopadhyay - CrystEngComm, 2021 - pubs.rsc.org
Two new zinc (II) complexes,[{N (CN) 2} Zn (L1) Zn {μ-1, 5-N (CN) 2}] 2 (1) and [{μ-1, 5-N
(CN) 2}{N (CN) 2} Zn (L2) Zn {μ-1, 5-N (CN) 2}] n (2){H2L1= 2, 2′-[(2, 2-dimethyl-1, 3 …

Intramolecular spodium bonds in Zn (II) complexes: insights from theory and experiment

M Karmakar, A Frontera, S Chattopadhyay… - International Journal of …, 2020 - mdpi.com
Two new dinuclear zinc (II) complexes,[Zn2 (µ 1, 3-OAc)(L1) 2] I· MeOH (1) and [Zn2 (µ 1, 3-
OAc)(L2)(NCS)](2),(where HL1= 2-(((3-(dimethylamino) propyl) amino) methyl)-6-methoxy …

Aerogen Bond, Halogen Bond, Chalcogen Bond, Pnictogen Bond, Tetrel Bond, Triel Bond... Why So Many Names?

R Taylor - Crystal Growth & Design, 2024 - ACS Publications
The nomenclature exemplified in this paper's title has more terms than necessary. It
conceals the often-similar physical natures of the noncovalent interactions that it names, and …

Spodium bonding in five coordinated Zn (II): A new player in crystal engineering?

RM Gomila, A Bauzá, TJ Mooibroek, A Frontera - CrystEngComm, 2021 - pubs.rsc.org
This manuscript evidences the existence and importance of spodium bonds (SpB) in solid
state structures involving five-coordinated square-pyramidal Zn (II) spodium atoms. Four …

Coordination versus spodium bonds in dinuclear Zn (ii) and Cd (ii) complexes with a dithiophosphate ligand

P Kumar, A Frontera, SK Pandey - New Journal of Chemistry, 2021 - pubs.rsc.org
The important role of spodium bonding (SpB) in Zn (II) and Cd (II) complexes is highlighted
in this feature article. SpB has been recommended to distinguish coordination bonds (high …

Experimental and Theoretical Study of Tetrel Bonding and Noncovalent Interactions in Hemidirected Lead (II) Phosphorodithioates: An Implication on Crystal …

P Kumar, T Firdoos, RM Gomila, A Frontera… - Crystal Growth & …, 2023 - ACS Publications
The importance of tetrel bonds (TtBs) in spontaneous self-assembly has been highlighted in
two new lead (II) complexes: ie Pb [S2P {OC6H4 (4-C (CH3) 3)} 2] 2 (1) and Pb [S2P …

Non-covalent bonds in group 1 and group 2 elements: the 'alkalene bond'

A Das, E Arunan - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
The non-covalent bonds formed by group 1 and group 2 elements were systematically
analysed by ab initio calculations at the MP2/aug-cc-pVDZ (for Ca, 6-311++ G (2df, p) basis …