The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Among the most significant advances in organic synthesis over the past few decades are
those associated with the development of transition metal complexes for their use as …

1, 3, 5-Triazo-2, 4, 6-triphosphorine-2, 2, 4, 4, 6, 6-tetrachloride (TAPC) was found to be an
efficient promoter for the oxidation of sulfides and deoxygenation of sulfoxides. Excellent …

A copper-mediated methylthiolation of aryl halides with the widely available DMSO is
described. The procedure tolerates a series of functional groups such as methoxy, nitro …

A new protocol for the coupling of aryl iodides with thiophenols and alkanethiols catalyzed
by copper nanoparticles under ligand‐free condition has been developed. A variety of …

The photocatalytic deoxygenation of sulfoxides to generate sulfides facilitated by either Ir
[(dF (CF3) ppy) 2 (dtbbpy)] PF6 or fac-Ir (ppy) 3 is reported. Mechanistic studies indicate that …

A scalable reduction of sulfoxides to sulfides in a sustainable way remains an unmet
challenge. This report discloses an electrochemical reduction of sulfoxides on a large scale …

A novel method for the reduction of sulfoxides and pyridine N-oxides using a silane and a
catalytic amount of MoO2Cl2 in excellent yields and with a wide functional group tolerance …

HAPpy catalysts: Hydroxyapatite‐supported gold nanoparticles efficiently catalyze the
deoxygenation of amides, sulfoxides, and pyridine N‐oxides, with silanes as reductants, to …

A green, efficient, photoinduced synthesis of arylboronic esters and aryl sulfides has been
developed. Bench stable arylazo sulfones were used as radical precursors for a …