Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …
polaritons, are formed due to quantum light–matter interactions. With the experimental …
The rise and current status of polaritonic photochemistry and photophysics
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
Molecular chemistry in cavity strong coupling
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …
matter interactions and so-called polaritonic states with intriguing properties, halfway …
Simulating molecular polaritons in the collective regime using few-molecule models
JB Pérez-Sánchez, A Koner… - Proceedings of the …, 2023 - National Acad Sciences
The study of molecular polaritons beyond simple quantum emitter ensemble models (eg,
Tavis–Cummings) is challenging due to the large dimensionality of these systems and the …
Tavis–Cummings) is challenging due to the large dimensionality of these systems and the …
Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
Sub-picosecond collapse of molecular polaritons to pure molecular transition in plasmonic photoswitch-nanoantennas
Molecular polaritons are hybrid light-matter states that emerge when a molecular transition
strongly interacts with photons in a resonator. At optical frequencies, this interaction unlocks …
strongly interacts with photons in a resonator. At optical frequencies, this interaction unlocks …
Advances in ultrafast plasmonics
In the past 20 years, we have reached a broad understanding of many light-driven
phenomena in nanoscale systems. The temporal dynamics of the excited states are instead …
phenomena in nanoscale systems. The temporal dynamics of the excited states are instead …
Cavity Born–Oppenheimer Hartree–Fock ansatz: Light–matter properties of strongly coupled molecular ensembles
Experimental studies indicate that optical cavities can affect chemical reactions through
either vibrational or electronic strong coupling and the quantized cavity modes. However …
either vibrational or electronic strong coupling and the quantized cavity modes. However …
Toward molecular chiral polaritons
Coupling between light and material excitations underlies a wide range of optical
phenomena. Polaritons are eigenstates of a coupled system with a hybridized wave …
phenomena. Polaritons are eigenstates of a coupled system with a hybridized wave …
Multi-scale molecular dynamics simulations of enhanced energy transfer in organic molecules under strong coupling
Exciton transport can be enhanced in the strong coupling regime where excitons hybridize
with confined light modes to form polaritons. Because polaritons have group velocity, their …
with confined light modes to form polaritons. Because polaritons have group velocity, their …