Polymer mechanochemistry-enabled pericyclic reactions

E Izak-Nau, D Campagna, C Baumann, R Göstl - Polymer Chemistry, 2020 - pubs.rsc.org
Over the past decades, it became clear that next to heat and light, pericyclic reactions can be
induced mechanochemically when the reacting motifs are embedded as latent force …

Experimental polymer mechanochemistry and its interpretational frameworks

S Akbulatov, R Boulatov - ChemPhysChem, 2017 - Wiley Online Library
Polymer mechanochemistry is an emerging field at the interface of chemistry, materials
science, physics and engineering. It aims at understanding and exploiting unique reactivities …

π-extended anthracenes as sensitive probes for mechanical stress

R Göstl, RP Sijbesma - Chemical science, 2016 - pubs.rsc.org
Smart molecular systems having the ability to report on mechanical strain or failure in
polymers via alteration of their optical properties are of great interest in materials science …

Covalent bond scission in the Mullins effect of a filled elastomer: real‐time visualization with mechanoluminescence

JM Clough, C Creton, SL Craig… - Advanced Functional …, 2016 - Wiley Online Library
Strain‐induced light emission from mechanoluminescent cross‐linkers in silica‐filled poly
(dimethylsiloxane) demonstrates that covalent bond scission contributes significantly to …

Novel reversible mechanochromic elastomer with high sensitivity: bond scission and bending-induced multicolor switching

T Wang, N Zhang, J Dai, Z Li, W Bai… - ACS Applied Materials & …, 2017 - ACS Publications
Although the rational designed mechanochromic polymer (MCP) materials have evoked
major interest and experienced significant progress recently, it is still a great challenge to …

Tailoring the properties of optical force probes for polymer mechanochemistry

S He, M Stratigaki, SP Centeno… - … –A European Journal, 2021 - Wiley Online Library
The correlation of mechanical properties of polymer materials with those of their molecular
constituents is the foundation for their holistic comprehension and eventually for improved …

An engineer's introduction to mechanophores

N Deneke, ML Rencheck, CS Davis - Soft Matter, 2020 - pubs.rsc.org
Mechanophores (MPs) are a class of stimuli-responsive materials that are of increasing
interest to engineers due to their potential applications as stress sensors. These …

Probing force with mechanobase‐induced chemiluminescence

JM Clough, A Balan, TLJ van Daal… - Angewandte Chemie …, 2016 - Wiley Online Library
Mechanophores capable of releasing N‐heterocyclic carbene (NHC), a strong base, are
combined with triggerable chemiluminescent substrates to give a novel system for …

Empowering self-reporting polymer blends with orthogonal optical properties responsive in a broader force range

M Wu, Z Guo, W He, W Yuan, Y Chen - Chemical Science, 2021 - pubs.rsc.org
Self-reporting polymers, which can indicate damage with perceptible optical signals in a
tailored force range, are useful as stress-sensitive sensors. We demonstrate a simple …

The “labile” chemical bond: a perspective on mechanochemistry in polymers

WH Binder - Polymer, 2020 - Elsevier
The view on macromolecules has expanded significantly since Staudinger's hypothesis 100
years ago. Currently noncovalent bonds are ranked equally important to their covalent …