Polymer mechanochemistry-enabled pericyclic reactions
Over the past decades, it became clear that next to heat and light, pericyclic reactions can be
induced mechanochemically when the reacting motifs are embedded as latent force …
induced mechanochemically when the reacting motifs are embedded as latent force …
Experimental polymer mechanochemistry and its interpretational frameworks
S Akbulatov, R Boulatov - ChemPhysChem, 2017 - Wiley Online Library
Polymer mechanochemistry is an emerging field at the interface of chemistry, materials
science, physics and engineering. It aims at understanding and exploiting unique reactivities …
science, physics and engineering. It aims at understanding and exploiting unique reactivities …
π-extended anthracenes as sensitive probes for mechanical stress
R Göstl, RP Sijbesma - Chemical science, 2016 - pubs.rsc.org
Smart molecular systems having the ability to report on mechanical strain or failure in
polymers via alteration of their optical properties are of great interest in materials science …
polymers via alteration of their optical properties are of great interest in materials science …
Covalent bond scission in the Mullins effect of a filled elastomer: real‐time visualization with mechanoluminescence
Strain‐induced light emission from mechanoluminescent cross‐linkers in silica‐filled poly
(dimethylsiloxane) demonstrates that covalent bond scission contributes significantly to …
(dimethylsiloxane) demonstrates that covalent bond scission contributes significantly to …
Novel reversible mechanochromic elastomer with high sensitivity: bond scission and bending-induced multicolor switching
T Wang, N Zhang, J Dai, Z Li, W Bai… - ACS Applied Materials & …, 2017 - ACS Publications
Although the rational designed mechanochromic polymer (MCP) materials have evoked
major interest and experienced significant progress recently, it is still a great challenge to …
major interest and experienced significant progress recently, it is still a great challenge to …
Tailoring the properties of optical force probes for polymer mechanochemistry
S He, M Stratigaki, SP Centeno… - … –A European Journal, 2021 - Wiley Online Library
The correlation of mechanical properties of polymer materials with those of their molecular
constituents is the foundation for their holistic comprehension and eventually for improved …
constituents is the foundation for their holistic comprehension and eventually for improved …
An engineer's introduction to mechanophores
Mechanophores (MPs) are a class of stimuli-responsive materials that are of increasing
interest to engineers due to their potential applications as stress sensors. These …
interest to engineers due to their potential applications as stress sensors. These …
Probing force with mechanobase‐induced chemiluminescence
Mechanophores capable of releasing N‐heterocyclic carbene (NHC), a strong base, are
combined with triggerable chemiluminescent substrates to give a novel system for …
combined with triggerable chemiluminescent substrates to give a novel system for …
Empowering self-reporting polymer blends with orthogonal optical properties responsive in a broader force range
M Wu, Z Guo, W He, W Yuan, Y Chen - Chemical Science, 2021 - pubs.rsc.org
Self-reporting polymers, which can indicate damage with perceptible optical signals in a
tailored force range, are useful as stress-sensitive sensors. We demonstrate a simple …
tailored force range, are useful as stress-sensitive sensors. We demonstrate a simple …
The “labile” chemical bond: a perspective on mechanochemistry in polymers
WH Binder - Polymer, 2020 - Elsevier
The view on macromolecules has expanded significantly since Staudinger's hypothesis 100
years ago. Currently noncovalent bonds are ranked equally important to their covalent …
years ago. Currently noncovalent bonds are ranked equally important to their covalent …