Trends in the Diels–Alder reaction in polymer chemistry

B Briou, B Améduri, B Boutevin - Chemical Society Reviews, 2021 - pubs.rsc.org
The Diels–Alder (DA) reaction is regarded as quite a useful strategy in organic and
macromolecular syntheses. The reversibility of this reaction and the advent of self-repair …

Dynamic bonds: adaptable timescales for responsive materials

SV Wanasinghe, OJ Dodo… - Angewandte Chemie, 2022 - Wiley Online Library
Dynamic bonds introduce unique properties such as self‐healing, recyclability, shape
memory, and malleability to polymers. Significant efforts have been made to synthesize a …

Achieving controlled biomolecule–biomaterial conjugation

CD Spicer, ET Pashuck, MM Stevens - Chemical reviews, 2018 - ACS Publications
The conjugation of biomolecules can impart materials with the bioactivity necessary to
modulate specific cell behaviors. While the biological roles of particular polypeptide …

The furan/maleimide Diels–Alder reaction: A versatile click–unclick tool in macromolecular synthesis

A Gandini - Progress in Polymer Science, 2013 - Elsevier
The purpose of this review is to provide a critical survey covering a few decades of growing
interest in the application to polymer chemistry of the Diels–Alder (DA) reaction between …

Diels–Alder “click” reactions: recent applications in polymer and material science

MA Tasdelen - Polymer Chemistry, 2011 - pubs.rsc.org
The “click” chemistry concept is based on utilizing rapid reactions which are efficient,
versatile, and selective. Indeed, Diels–Alder (DA) reactions fulfill most of the requirements …

Self-healing systems based on disulfide–thiol exchange reactions

M Pepels, I Filot, B Klumperman, H Goossens - Polymer Chemistry, 2013 - pubs.rsc.org
New thermoset systems based on disulfide bonds were synthesized with self-healing
capabilities. The self-healing mechanism is not related to disulfide–disulfide exchange …

Standing on the shoulders of Hermann Staudinger: Post‐polymerization modification from past to present

KA Günay, P Theato, HA Klok - Journal of Polymer Science Part …, 2013 - Wiley Online Library
With a span as long as the history of polymer science itself, post‐polymerization modification
represents a versatile platform for the preparation of diversely functionalized polymers from …

Study of the Diels–Alder and retro-Diels–Alder reaction between furan derivatives and maleimide for the creation of new materials

V Froidevaux, M Borne, E Laborbe, R Auvergne… - Rsc Advances, 2015 - pubs.rsc.org
The Diels–Alder reaction leads to a mixture of two diastereomers, one called endo and the
other one exo. The cyclo-reversion temperature of the first one is lower than the exo adduct …

A critical appraisal of the potential of self healing polymeric coatings

SJ García, HR Fischer, S Van Der Zwaag - Progress in Organic Coatings, 2011 - Elsevier
Several approaches and concepts to self healing materials have appeared in the literature
over the last years, all presenting advantages and disadvantages, but definitely showing the …

The potential of microencapsulated self-healing materials for microcracks recovery in self-healing composite systems: A review

H Ullah, KA M Azizli, ZB Man, MBC Ismail… - Polymer reviews, 2016 - Taylor & Francis
The autonomic self-healing materials based on microcapsules have made major
advancements for the repairing of microcracks in polymers and polymer composite systems …