Metallaphotoredox: the merger of photoredox and transition metal catalysis
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …
Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis
NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
Strategies to generate nitrogen-centered radicals that may rely on photoredox catalysis: development in reaction methodology and applications in organic synthesis
For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …
years, but such is the pace of progress that we will overlap very little with earlier …
Ligand‐to‐metal charge transfer (LMCT) photochemistry at 3d‐metal complexes: an emerging tool for sustainable organic synthesis
F Juliá - ChemCatChem, 2022 - Wiley Online Library
Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …
reactivity of these compounds in organic synthesis has been historically overlooked. The …
Dual metalation in a two-dimensional covalent organic framework for photocatalytic C–N cross-coupling reactions
Covalent organic frameworks (COFs) are promising hosts in heterogeneous catalysis.
Herein, we report a dual metalation strategy in a single two-dimensional-COF TpBpy for …
Herein, we report a dual metalation strategy in a single two-dimensional-COF TpBpy for …
Nickel and palladium catalysis: Stronger demand than ever
VM Chernyshev, VP Ananikov - Acs Catalysis, 2022 - ACS Publications
Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …
Interrogating the mechanistic features of Ni (I)-mediated aryl iodide oxidative addition using electroanalytical and statistical modeling techniques
While the oxidative addition of Ni (I) to aryl iodides has been commonly proposed in catalytic
methods, an in-depth mechanistic understanding of this fundamental process is still lacking …
methods, an in-depth mechanistic understanding of this fundamental process is still lacking …
Oxidative addition of aryl halides to a Ni (I)-bipyridine complex
The oxidative addition of aryl halides to bipyridine-or phenanthroline-ligated nickel (I) is a
commonly proposed step in nickel catalysis. However, there is a scarcity of complexes of this …
commonly proposed step in nickel catalysis. However, there is a scarcity of complexes of this …
Nickel‐catalyzed C‐heteroatom cross‐coupling reactions under mild conditions via facilitated reductive elimination
The formation of C‐heteroatom bonds represents an important type of bond‐forming
reaction in organic synthesis and often provides a fast and efficient access to privileged …
reaction in organic synthesis and often provides a fast and efficient access to privileged …