The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …

Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

Covalent organic frameworks (COFs) are promising hosts in heterogeneous catalysis.
Herein, we report a dual metalation strategy in a single two-dimensional-COF TpBpy for …

Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

While the oxidative addition of Ni (I) to aryl iodides has been commonly proposed in catalytic
methods, an in-depth mechanistic understanding of this fundamental process is still lacking …

The oxidative addition of aryl halides to bipyridine-or phenanthroline-ligated nickel (I) is a
commonly proposed step in nickel catalysis. However, there is a scarcity of complexes of this …

The formation of C‐heteroatom bonds represents an important type of bond‐forming
reaction in organic synthesis and often provides a fast and efficient access to privileged …