Mesocrystals—Ordered nanoparticle superstructures

RQ Song, H Cölfen - Advanced materials, 2010 - Wiley Online Library
Mesocrystals are 3D ordered nanoparticle superstructures, often with internal porosity,
which receive much recent research interest. While more and more mesocrystal systems are …

Single-crystal polymers (SCPs): from 1D to 3D architectures

M Wang, Y Jin, W Zhang, Y Zhao - Chemical Society Reviews, 2023 - pubs.rsc.org
Single-crystal polymers (SCPs) with unambiguous chemical structures at atomic-level
resolutions have attracted great attention. Obtaining precise structural information of these …

In situ mechanical reinforcement of polymer hydrogels via metal-coordinated crosslink mineralization

S Kim, AU Regitsky, J Song, J Ilavsky… - Nature …, 2021 - nature.com
Biological organic-inorganic materials remain a popular source of inspiration for bioinspired
materials design and engineering. Inspired by the self-assembling metal-reinforced mussel …

Tuning hardness in calcite by incorporation of amino acids

YY Kim, JD Carloni, B Demarchi, D Sparks, DG Reid… - Nature materials, 2016 - nature.com
Structural biominerals are inorganic/organic composites that exhibit remarkable mechanical
properties. However, the structure–property relationships of even the simplest building unit …

An artificial biomineral formed by incorporation of copolymer micelles in calcite crystals

YY Kim, K Ganesan, P Yang, AN Kulak, S Borukhin… - Nature materials, 2011 - nature.com
Biominerals exhibit morphologies, hierarchical ordering and properties that invariably
surpass those of their synthetic counterparts. A key feature of these materials, which sets …

Crystal growth of calcium carbonate in hydrogels as a model of biomineralization

E Asenath‐Smith, H Li, EC Keene… - Advanced Functional …, 2012 - Wiley Online Library
In recent years, the prevalence of hydrogel‐like organic matrices in biomineralization has
gained attention as a route to synthesizing a diverse range of crystalline structures. Here …

Visualizing the 3D internal structure of calcite single crystals grown in agarose hydrogels

H Li, HL Xin, DA Muller, LA Estroff - Science, 2009 - science.org
Single crystals are usually faceted solids with homogeneous chemical compositions.
Biogenic and synthetic calcite single crystals, however, have been found to incorporate …

Additive controlled crystallization

RQ Song, H Cölfen - CrystEngComm, 2011 - pubs.rsc.org
Additives play a decisive role in crystallization processes. We survey the ongoing efforts in
the realm of additive-controlled crystallization. Emphasis is placed on the commonly used …

Crystal growth with macromolecular additives

AG Shtukenberg, MD Ward, B Kahr - Chemical reviews, 2017 - ACS Publications
Interactions of macromolecules with growing crystalline surfaces play an important role in
biomineralization, determine survival of some organisms at low temperatures, and offer a …

Direct observation of mineral–organic composite formation reveals occlusion mechanism

K Rae Cho, YY Kim, P Yang, W Cai, H Pan… - Nature …, 2016 - nature.com
Manipulation of inorganic materials with organic macromolecules enables organisms to
create biominerals such as bones and seashells, where occlusion of biomacromolecules …