Hydrazone-based switches, metallo-assemblies and sensors

X Su, I Aprahamian - Chemical Society Reviews, 2014 - pubs.rsc.org
The hydrazone functional group has been extensively studied and used in the context of
supramolecular chemistry. Its pervasiveness and versatility can be attributed to its ease of …

Metallosupramolecular grid complexes: Towards nanostructured materials with high-tech applications

JG Hardy - Chemical Society Reviews, 2013 - pubs.rsc.org
Metallosupramolecular grid complexes (hereafter referred to as metallogrids) are well-
defined oligonuclear metal ion complexes involving essentially planar arrays of the metal …

A carboxylate-bridged Ni II8 cluster with a distorted cubane topology: structure, magnetism and density functional studies

H Arora, J Cano, F Lloret, R Mukherjee - Dalton Transactions, 2016 - pubs.rsc.org
Using a dicarboxylate ligand appended with (2-pyridyl) ethylamine unit, a new cluster [NiII8
(L4) 6 (DMF) 2 (CH3OH) 2 (H2O) 6][ClO4] 4· 2CH3OH· 2CH3CO2C2H5 (1)[L4 (2−): 3-[N-{2 …

Two low-dimensional Schiff base copper (I/II) complexes: synthesis, characterization and catalytic activity for degradation of organic dyes

XJ Hong, X Liu, JB Zhang, CL Lin, X Wu, YJ Ou… - …, 2014 - pubs.rsc.org
Two low-dimensional oxime-containing Schiff base copper (I/II) complexes with iodine–
copper cluster [Cu2I4] 2− bridges, namely,{[CuII4I3 (pop) 4] 2 (CuI2I4)}·(CH3CN) 2· H2O (2) …

Fascinating interlocked triacontanuclear giant nanocages

S Bala, S Akhtar, JL Liu, GZ Huang, SG Wu… - Chemical …, 2021 - pubs.rsc.org
We report herein three air, thermal and solvent stable interlocked triacontanuclear giant
nanocages, generated using a node and spacer concept. Interestingly, the crystal structures …

Valence directed binding mode of [2× 2] iron grids of an unsymmetrical picolinic hydrazone based ligand

SM Hossain, A Lakma, RN Pradhan, S Demeshko… - Dalton …, 2017 - pubs.rsc.org
A new unsymmetrical ditopic ligand H2L was used to synthesize two [2× 2] grid type
tetranuclear trivalent and mixed-valent FeIII4, FeII2FeIII2 complexes, respectively. Both …

Tetranuclear Mn II, Co II, Cu II and Zn II grid complexes of an unsymmetrical ditopic ligand: synthesis, structure, redox and magnetic properties

A Lakma, SM Hossain, J van Leusen, P Kögerler… - Dalton …, 2019 - pubs.rsc.org
Synthesis towards the preparation of an unsymmetrical binucleating Schiff-base
ligand,(H2L) is discussed. It has been synthesized by reacting methyl 6-(hydrazinecarbonyl) …

Anion coordination directed synthesis patterns for [Ni 4] aggregates: structural changes for thiocyanate coordination and ligand arm hydrolysis

M Das, R Herchel, Z Trávníček, V Bertolasi… - New Journal of …, 2018 - pubs.rsc.org
The coordination reactivity of ligand H5L1 (2, 6-bis-{(1, 3-dihydroxy-2-methylpropan-2-
ylimino) methyl}-4-methylphenol) toward nickel (II) ions in the presence of two different …

A ring of grids: a giant spin-crossover cluster

T Shiga, M Tachibana, H Sagayama, R Kumai… - Chemical …, 2021 - pubs.rsc.org
Mononuclear and icosanuclear spin-crossover complexes,[FeII (HL) 2](BF4) 2 (1) and
[FeII20 (L) 24](BF4) 16 (2), were synthesized using an asymmetric multidentate ligand (HL) …

[PDF][PDF] Crystal structure and Hirshfeld surface analysis of (E)-2, 4-di-tert-butyl-6-[(3-chloro-4-methylphenylimino) methyl] phenol

S Kansiz, M Macit, N Dege… - Acta Crystallographica …, 2018 - journals.iucr.org
The title Schiff base compound, C22H28ClNO, shows mirror symmetry with all its non-H
atoms, except the tert-butyl groups, located on the mirror plane. There is an intramolecular O …