Cl atoms-initiated degradation of 1-Chlorobutane and 2-Chlorobutane: Kinetics, product analysis and atmospheric implications

B Kar, B Rajakumar - Chemosphere, 2023 - Elsevier
The relative rate method was employed to investigate the kinetics of the Cl-initiated
reactions of 1-chlorobutane (1-CB) and 2-chlorobutane (2-CB) over 263–363 K, and the …

A theoretical kinetics study on low-temperature reactions of methyl acetate radicals with molecular oxygen

Q Meng, X Zhao, L Zhang, P Zhang, L Sheng - Combustion and Flame, 2018 - Elsevier
Theoratical studies on the chemistry of methyl acetate radicals with molecular oxygen was
conducted to get further understanding of biodiesel combustion. Reactions of the first …

Theoretical Studies of the Reactions CFxH3−xCOOR+Cl and CF3COOCH3+OH

FY Bai, XL Zhu, ZM Jia, X Wang, YQ Sun… - …, 2015 - Wiley Online Library
The mechanism and kinetics of the reactions of CF3COOCH2CH3, CF2HCOOCH3, and
CF3COOCH3 with Cl and OH radicals are studied using the B3LYP, MP2, BHandHLYP, and …

Kinetics and mechanism of the reactions of OH radicals with p-nitroaniline in gas-phase and aqueous solution

M Li, H Cao, D Han, X Li, M He - Computational and Theoretical Chemistry, 2015 - Elsevier
The OH-initiated oxidation of p-nitroaniline (p-NA) was studied both in gas phase and
aqueous solution. The calculated results show that addition reactions between p-NA and OH …

Theoretical investigation on gas-phase reaction of CF3CH2OCH3 with OH radicals and fate of alkoxy radicals (CF3CH (O) OCH3/CF3CH2OCH2O)

BK Mishra, M Lily, RC Deka, AK Chandra - Journal of Molecular Graphics …, 2014 - Elsevier
Detailed theoretical investigation has been performed on the mechanism, kinetics and
thermochemistry of the gas phase reactions of CF 3 CH 2 OCH 3 (HFE-263fb2) with OH …

Theoretical study of the interaction between pyridine derivatives and atomic chlorine. Substituent effect and nature of the bonding

D Sutradhar, T Zeegers-Huyskens… - Molecular Physics, 2015 - Taylor & Francis
The interaction of pyridine derivatives (H, 4-NH2, 4-CH3, 4-F, 4-CN, 4-NO2) with atomic
chlorine is investigated theoretically by the density functional theory (DFT)-based LC …

A theoretical investigation on kinetics, mechanism, and thermochemistry of the gas-phase reactions of methyl fluoroacetate with OH radicals and fate of alkoxy radical

BK Mishra, RC Deka - The Journal of Physical Chemistry A, 2014 - ACS Publications
We theoretically investigated OH-initiated hydrogen abstraction reactions of methyl
fluoroacetate (MFA) CH2FC (O) OCH3 at the MPWB1K level of theory in conjunction with the …

Theoretical study on the gas-phase reactions of ethyl butyrate with OH radicals at 298 K

NK Gour, RC Deka, HJ Singh, BK Mishra - Monatshefte für Chemie …, 2014 - Springer
Detailed theoretical investigation has been carried out on the mechanism, kinetics, and
thermochemistry of the gas-phase reactions of CH 3 CH 2 CH 2 C (O) OCH 2 CH 3 with OH …

Theoretical investigation of the mechanisms and dynamics of the reaction CHF2OCF2CHFCl+Cl

F Bai, Y Sun, X Wang, Z Jia, R Wang, X Pan - Journal of molecular …, 2014 - Springer
The reaction of CHF 2 OCF 2 CHFCl with atomic chlorine was studied using B3LYP/6-311G
(d, p), BHandHLYP/6-311G (d, p), and M06-2X/6-311G (d, p) methods and further using …

Theoretical study of the S… Cl interaction between sulfides and atomic chlorine. Nature and strength of the two-center three-electron bond

D Sutradhar, T Zeegers-Huyskens… - Journal of Molecular …, 2017 - Elsevier
The interaction between sulfides (H 2 S, CH 3 SH, CH 3 CH 2 SH, CH 3 SCH 3 and CH 3
SCH 2 F) and atomic chlorine is investigated using DFT based LC-BLYP and CCSD (T) …