Tris (pyrazolyl) borates, first reported about 40 years ago, are a very useful class of
monoanionic, nitrogen-based, auxiliary ligands in coordination and organometallic and …

The reduction of nitrite to nitric oxide in dissimilatory denitrification is carried out by copper
nitrite reductases (CuNIRs) via a type 2 copper site. Extended studies on CuNIRs in …

This book deals with polypyrazolylborates (scorpionates), a class of ligands known since
1966, but becoming rapidly popular with inorganic, organometallic and coordination …

In 1966 Trofimenko first reported the synthesis of a class of molecule that would become a
valuable ligand system in modern coordination chemistry 1., 2.. Specifically, the system that …

Copper (I) complexes with tripodal nitrogen-containing neutral ligands such as tris (3, 5-
diisopropyl-1-pyrazolyl) methane (L1 ') and tris (3-tertiary-butyl-5-isopropyl-1-pyrazolyl) …

The syntheses, spectroscopy, and structures of silver (I) hydrotris (3, 5-bis (trifluoromethyl)
pyrazolyl) borate complexes with tetrahydrofuran (THF), toluene, carbon monoxide …

Despite the widespread use of tris (pyrazolyl) borate ligands, their isoelectronic, neutral
analogs, tris (pyrazolyl) methane ligands, have not been extensively studied. By use of …

This paper introduces a sterically encumbered, strong-field tris (diisopropylphosphino)
borate ligand,[PhBPiPr3]([PhBPiPr3]=[PhB (CH2PiPr2) 3]-), to probe aspects of its …

Ligation of thiolate sulfur to copper at the active sites of quite a number of copper proteins
has been established either by X-ray crystallographic and/or by spectroscopic studies. In …

Tris (pyrazolyl) borates (Tp x) have become one of the most broadly used polydentate
anionic ligands in coordination chemistry and catalysis since Trofimenko introduced them in …