We present an update and revision to our 2010 review on the topic of proton-coupled
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …

Conspectus The electrocatalytic CO2 reduction reaction (CO2RR) to generate fixed forms of
carbons that have commercial value is a lucrative avenue to ameliorate the growing …

In the context of a carbon neutral economy, catalytic CO2 hydrogenation to methanol is one
crucial technology for CO2 mitigation providing solutions for manufacturing future fuels …

Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Propelled by the vision of carbon-neutral energy systems, heterogeneous hydrogenation of
CO2 to formic acid/formate, a liquid hydrogen carrier, has been intensively studied as a …

Knowledge and foundational understanding of phenomena associated with the behavior of
materials at the nanoscale is one of the key scientific challenges toward a sustainable …

The study and application of transition metal hydrides (TMHs) has been an active area of
chemical research since the early 1960s, for energy storage, through the reduction of …

This review provides a comprehensive view of the application of first-row transition metals in
asymmetric hydrogenation and asymmetric transfer hydrogenation. The catalytic behavior of …

Catalytic hydrogenation and dehydrogenation reactions form the core of the modern
chemical industry. This vast class of reactions is found in any part of chemical synthesis …