The development of catalytic methodologies involving the formation of C–C bonds to enable
the generation of cyclic systems constitutes a field of great relevance in synthetic organic …

Polymers are at the epicentre of modern technological progress and the associated
environmental pollution. Considerations of both polymer functionality and lifecycle are …

Metallacyclopentadienes, which possess two M–C (sp2) bonds and feature the structure of
M (CR1CR2–CR3CR4), are an important class of five-membered metallacycles. They are …

Conspectus Metalloles are derivatives of cyclopentadiene in which the methylene unit is
replaced by a heteroatom, such as S, Se, Te, N, P, As, Sb, Bi, Si, Ge, Sn, B, Al, Ga, and so …

Perfluorination: The fully fluorinated analogue of pentaphenylborole (see structure; B gray, C
black, F green) has been prepared using successive transmetallation reactions involving Zr …

The mechanism of the copper-free Sonogashira cross-coupling was investigated using a
model reaction with differently para-substituted phenylacetylenes and 4-iodobenzotrifluoride …

In this full article, detailed development of a catalytic decarbonylation of conjugated
monoynones to synthesize disubstituted alkynes is described. The reaction scope and …

An efficient C (sp3)–H bond activation and intramolecular amination reaction via palladium
catalysis at the β-position of carboxyamides to make β-lactams was described. The …

The Fritsch–Buttenberg–Wiechell rearrangement of carbene/carbenoid intermediates has
evolved into a valuable synthetic methodology for the preparation of polyyne structures …

The paper gives a review of publications on polymers with conjugated matrices (PPy, PTh,
PAni, hydrocarbon or mixed chains…) which incorporate metallocene complexes (Fe, Ru …