Electron-transfer reactions between ions and molecules in solution have been the subject of
considerable experimental study during the past three decades. Experimental results have …

Despite the multitude of formalisms, there is general agreement that the crux of the electron
transfer problem is the change in equilibrium nuclear configurations that occurs when a …

The phenomenon of Extended X-Ray Absorption Fine Structure (EXAFS) has been known
for some time and was first treated theoretically by Kronig in the 1930s. Recent …

Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

Reported here are results of theoretical calculations on Fe (H2O) 63+, Fe (H2O) 5 (OH) 2+,
three isomers of Fe (H2O) 4 (OH) 2+, and Fe (H2O) 3 (OH) 2+, which investigate the …

The genesis of the exploration of electron transfer (ET) in the condensed phase dates back
to the origins of chemistry in the nineteenth century. In 1808 Humphry Davy observed [1] that …

Electron flow through proteins and protein assemblies in the photosynthetic and respiratory
machinery commonly occurs between metal centers or other redox cofactors that are …

The solvent plays an important role in many chemical reactions, especially charge transfer
where there is typically a substantial change in electronic distribution between the initial and …

The kinetics of several fast heterogeneous electron-transfer reactions were investigated by
steady-state voltammetry at nanoelectrodes and scanning electrochemical microscopy …

Equilibrium and kinetic Fe isotope fractionation between aqueous ferrous and ferric species
measured over a range of chloride concentrations (0, 11, 110 mM Cl−) and at two …