Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets

JH Wang, ZY Li, M Yamashita, XH Bu - Coordination Chemistry Reviews, 2021 - Elsevier
Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

Heterotrimetallic complexes in molecular magnetism

M Andruh - Chemical Communications, 2018 - pubs.rsc.org
This paper reviews the most representative examples of heterometallic complexes
containing three different paramagnetic metal ions, focusing on their magnetic properties …

Modular approach towards functional multimetallic coordination clusters

J Kobylarczyk, E Kuzniak, M Liberka, S Chorazy… - Coordination Chemistry …, 2020 - Elsevier
Polynuclear coordination clusters (PCCs) provide considerable design capabilities towards
various functions based on structural non-rigidity and spin state transitions, optical …

Exact and density matrix renormalization group studies of two mixed spin- branched-chain models developed for a heterotrimetallic Fe-Mn-Cu coordination …

F Souza, LM Veríssimo, J Strečka, ML Lyra… - Physical Review B, 2020 - APS
The mixed-spin Ising-Heisenberg and Heisenberg branched chains whose magnetic
backbone consists of regularly alternating spins 1/2 and 5/2, the latter of which are …

Discrete versus chain assembly: hexacyanometallate linkers and macrocyclic {3d–4f} single-molecule magnet building blocks

S Dhers, HLC Feltham, M Rouzières, R Clérac… - Inorganic …, 2019 - ACS Publications
The self-assembly of macrocyclic tetranuclear 3d–4f single-molecule magnet (SMM)
building blocks,[CuII3TbIII (L Pr)(NO3) 2 (H2O)] NO3 (1), with K3 [MIII (CN) 6] linkers, where …

X-ray crystal structures of K+ and Rb+ salts of [W (CN) 6 (bpy)] 2− ion. The unusual cation–anion interactions and structure changes going from Li+ to Cs+ salts

M Hodorowicz, A Jurowska, J Szklarzewicz - CrystEngComm, 2021 - pubs.rsc.org
Complexes of the compounds K2 [W (CN) 6 (bpy)]· 3H2O (1) and Rb2 [W (CN) 6 (bpy)]· 3.5
H2O (2) were synthesized, structurally characterized, described and compared with the …

A rare isostructural series of 3d–4f cyanido-bridged heterometallic squares obtained by assembling [Fe III {HB (pz) 3}(CN) 3]− and Ln III ions: synthesis, X-ray structure …

MG Alexandru, D Visinescu, B Cula, S Shova… - Dalton …, 2021 - pubs.rsc.org
A new series of cyanido-bridged {FeIIILnIII} 2 neutral molecular squares of general formula
[Fe {HB (pz) 3}(CN)(μ-CN) 2Ln (NO3) 2 (pyim)(Ph3PO)] 2· 2CH3CN [Ln= Ce (1), Pr (2), Nd …

Design of 3d–4f molecular squares through the [Fe {(HB (pz) 3)}(CN) 3]− metalloligand

MG Alexandru, D Visinescu, S Shova… - Dalton …, 2018 - pubs.rsc.org
A new series of {FeIII2LnIII2} heterobimetallic squares of general formula [FeIII {HB (pz)
3}(CN)(μ-CN) 2Ln (pyim) x (NO3) 2 (H2O) y] 2· zH2O [Ln= La (1), Gd (2), Tb (3) and Dy …

The versatility of lithium cation coordination modes in salts with [W (CN) 6 (bpy)] 2− anions

M Hodorowicz, J Szklarzewicz, A Jurowska - CrystEngComm, 2020 - pubs.rsc.org
The synthesis and spectral and structural descriptions of two salts of formulas {[Li][Li (H2O)(μ-
CN) 3]}[W (CN) 3 (bpy)](1) and {Li}{[Li (μ-CN) 2][Li (μ-CN) 3] μ-Cl}[W (CN)(bpy)]· 2H2O (2) …

2D and 3D mixed M II/Cu II metal–organic frameworks (M= Ca and Sr) with N, N′-2, 6-pyridinebis (oxamate) and oxalate: preparation and magneto-structural study

TS Fernandes, WDC Melo, LHG Kalinke… - Dalton …, 2018 - pubs.rsc.org
Three heterobimetallic complexes of formula [Ca2Cu3 (mpyba) 2 (2-apyma)(H2O) 7]· 8.3
H2O (1),[Sr2Cu3 (mpyba) 2 (2-apyma)(H2O) 8]· 11.6 H2O (2) and [Sr4. 5Cu4 (mpyba) 4 …