Taming the cationic beast: novel developments in the synthesis and application of weakly coordinating anions

IM Riddlestone, A Kraft, J Schaefer… - Angewandte Chemie …, 2018 - Wiley Online Library
This Review gives a comprehensive overview of the most topical weakly coordinating
anions (WCAs) and contains information on WCA design, stability, and applications. As an …

<?ACS-CT-START-Insert ?>Update 1 of: <?ACS-CT-END-Insert ?>Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12

… <? ACS-CT-START-Insert?> Douvris<? ACS … - Chemical …, 2013 - ACS Publications
Polyhedral boranes and carborane clusters are characterized by delocalized electron
deficient bonding, meaning that there are too few valence electrons for bonding to be …

Boron science

NS Hosmane - New technologies and applications, 2011 - api.taylorfrancis.com
What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …

Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions

WS Tang, A Unemoto, W Zhou, V Stavila… - Energy & …, 2015 - pubs.rsc.org
Solid electrolytes with sufficiently high conductivities and stabilities are the elusive answer to
the inherent shortcomings of organic liquid electrolytes prevalent in today's rechargeable …

Carboranes in the chemist's toolbox

RN Grimes - Dalton Transactions, 2015 - pubs.rsc.org
Once seldom encountered outside of a few laboratories, carboranes are now everywhere,
playing a role in the development of a broad range of technologies encompassing organic …

Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12-

S Körbe, PJ Schreiber, J Michl - Chemical reviews, 2006 - ACS Publications
Polyhedral borane and carborane clusters are characterized by delocalized electron-
deficient bonding, meaning that there are too few valence electrons for bonding to be …

Are Methyl Groups Electron-Donating or Electron-Withdrawing in Boron Clusters? Permethylation of o-Carborane

F Teixidor, G Barberà, A Vaca, R Kivekäs… - Journal of the …, 2005 - ACS Publications
That methyl groups attached to carbon atoms are electron donors must not be generally
assumed. In boron clusters, Me groups on boron are electron withdrawing. At the B3LYP/6 …

Amphoteric reactivity of metal–oxygen complexes in oxidation reactions

M Sankaralingam, YM Lee, W Nam… - Coordination Chemistry …, 2018 - Elsevier
Mononuclear metal–oxygen species, such as metal-superoxo,-peroxo,-hydroperoxo and-
oxo complexes, are key intermediates involved in dioxygen activation and oxidation …

Order–Disorder Transitions and Superionic Conductivity in the Sodium nido-Undeca(carba)borates

WS Tang, M Dimitrievska, V Stavila, W Zhou… - Chemistry of …, 2017 - ACS Publications
The salt compounds NaB11H14, Na-7-CB10H13, Li-7-CB10H13, Na-7, 8-C2B9H12, and Na-
7, 9-C2B9H12 all contain geometrically similar, monocharged, nido-undeca (carba) borate …

Heavy Carbene Analogues: Donor‐Free Bismuthenium and Stibenium Ions

M Olaru, D Duvinage, E Lork, S Mebs… - Angewandte Chemie …, 2018 - Wiley Online Library
Kinetically stabilized congeners of carbenes, R2C, possessing six valence electrons (four
bonding electrons and two non‐bonding electrons) have been restricted to Group 14 …