Polymer synthesis in continuous flow reactors

N Zaquen, M Rubens, N Corrigan, J Xu… - Progress in Polymer …, 2020 - Elsevier
A variety of polymerizations has long been performed in continuous flow reactors on an
industrial scale; comparatively, on smaller scales, continuous polymerization methods have …

Continuous-flow microreactors for polymer synthesis: engineering principles and applications

Y Su, Y Song, L Xiang - Accounts on Sustainable Flow Chemistry, 2020 - Springer
Polymerization is widely involved in the fabrication of high-performance materials. With its
advantages, microreactors are typically applied to reaction processes which are limited by …

Hydrodynamics and mass transfer performance during the chemical oxidative polymerization of aniline in microreactors

Y Song, J Song, M Shang, W Xu, S Liu, B Wang… - Chemical Engineering …, 2018 - Elsevier
The hydrodynamics and mass transfer performance in the chemical oxidative polymerization
of aniline in capillary microreactors within the liquid-liquid slug flow regime were …

Improved photo-induced cobalt-mediated radical polymerization in continuous flow photoreactors

A Kermagoret, B Wenn, A Debuigne, C Jérôme… - Polymer …, 2015 - pubs.rsc.org
The implementation of cobalt-mediated radical polymerization (CMRP) for continuous
microreactor synthesis is described. We demonstrate how the utilization of flow …

Coil flow inversion as a route to control polymerization in microreactors

D Parida, CA Serra, DK Garg, Y Hoarau, F Bally… - …, 2014 - ACS Publications
Linear and branched polymers of 2-(dimethylamino) ethyl methacrylate (PDMAEMA) were
synthesized in flow by atom transfer radical polymerization (ATRP) and self-condensing …

Kinetics study of acrylic acid polymerization with a microreactor platform

L Qiu, K Wang, S Zhu, Y Lu, G Luo - Chemical Engineering Journal, 2016 - Elsevier
A microreactor platform with easily assembled reaction tubes is developed to study the
kinetics of acrylic acid polymerization in aqueous solutions. In this platform, two micromixers …

Production of dry-state ketoprofen-encapsulated PMMA NPs by coupling micromixer-assisted nanoprecipitation and spray drying

S Ding, CA Serra, N Anton, W Yu… - International Journal of …, 2019 - Elsevier
We present a two-step process to produce dry-state Ketoprofen-loaded poly (methyl
methacrylate) nanoparticles (NPs) with controllable size and tunable drug release profile. A …

Highly efficient reversible addition–fragmentation chain‐transfer polymerization in ethanol/water via flow chemistry

P Ye, PF Cao, Z Su, R Advincula - Polymer International, 2017 - Wiley Online Library
Utilization of a flow reactor under high pressure allows highly efficient polymer synthesis via
reversible addition–fragmentation chain‐transfer (RAFT) polymerization in an aqueous …

Hyperbranched PDMAEMA-functionalized SiO2 microparticles: ATRP polymerization and grafting in a continuous flow reactor

J Ge, Y Yin, EB Caldona, RC Advincula - MRS communications, 2022 - Springer
Flow chemistry offers high reaction yield, kinetic control, improved safety, reliability,
scalability, and greater degree of process control. Herein, hyperbranched polymer-grafted …

New microreactor designs for practical applications realized by additive manufacturing

P Löb - 2019 - books.rsc.org
Continuous processing is playing an increasing role in the development and manufacturing
of pharmaceuticals and fine chemicals. 1 Linked to this development is the interest in flow …