The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

High-oxidation-state 3d metal species have found a wide range of applications in modern
synthetic chemistry and materials science. They are also implicated as key reactive species …

Herein, we study the mechanism of iron-catalyzed direct synthesis of unprotected
aminoethers from olefins by a hydroxyl amine derived reagent using a wide range of …

Titanium and zirconium complexes carrying two 2, 6-bis (pyrrolyl) pyridine ligands have
been synthesized and characterized. The neutral complexes Ti (MePDP) 2 and Zr (MePDP) …

Reduction of previously reported iminyl radical (ArL) FeCl (• N (C6H4-pt Bu))(2) with
potassium graphite furnished the corresponding high-spin (S= 5/2) imido (ArL) Fe (N (C6H4 …

Transition‐metal‐catalyzed C—H bond amination reaction is an attractive method for the
synthesis of amines. Fueled by the growing interests in the development of economical and …

Aziridination has very recently been found to be catalyzed by heme and nonheme Fe
enzymes, opening the way to biotechnological developments. However, its mechanism is …

Imidyl and nitrene metal species play an important role in the N-functionalisation of
unreactive C–H bonds as well as the aziridination of olefines. We report on the synthesis of …

The 3d‐metal mediated nitrene transfer is under intense scrutiny due to its potential as an
atom economic and ecologically benign way for the directed amination of (un) functionalised …

Catalytic C− N bond formation by direct activation of C− H bonds offers wide synthetic
potential. En route to C− H amination, complexes with organic azides are critical precursors …