The main contributions in the field of first-row transition-metal-catalyzed (base-metal-
catalyzed) carbonylative transformations have been summarized and discussed. The …

While carbon monoxide (CO) gas has been extensively applied in the bulk chemical
industry, its intrinsic properties such as high toxicity, flammability, and special equipment …

The urea functionality is inherent to numerous bioactive compounds, including a variety of
clinically approved therapies. Urea containing compounds are increasingly used in …

A visible light-induced and exogenous photosensitizer-free, copper-catalyzed radical
aminocarbonylation of cycloketone oxime esters with CO gas and amines is developed. The …

The direct carbonylation of aromatic sp2 and unactivated sp3 C–H bonds of amides was
achieved via nickel/copper catalysis under atmospheric O2 with the assistance of a …

Carbonylation, an efficient and straightforward approach for installing a carbonyl group into
their parent compounds, is an important area in modern organic synthesis. This Review …

A cobalt-catalyzed C–H carbonylation of naphthylamides for the synthesis of benzo [cd]
indol-2 (1 H)-one scaffolds has been developed. The reaction employs a traceless directing …

Carbon monoxide is an indispensable C1 building block that has been recognized as a
potent feedstock for synthesizing carbonyl-containing molecules. Carbonylative reactions …

In this account, we review our efforts in the field of carbonylation reactions promoted by
palladium iodide-based catalysts, which have proven to be particularly efficient in diverse …

Methods to convert amines to formamides are of interest due to the many uses of
formamides as synthetic intermediates. These methods include stoichiometric reactions of …