Kinetics of chemical processes: From molecular to industrial scale
Combining spectroscopic and transient kinetic techniques provides access to the
identification and quantification of active sites and corresponding turnover frequencies of …
identification and quantification of active sites and corresponding turnover frequencies of …
[HTML][HTML] Simplifying the Temporal Analysis of Products reactor
Abstract The Temporal Analysis of Products (TAP) experiment provides an unparalleled
level of kinetic insight into heterogenous catalytic materials, but due to the complex and …
level of kinetic insight into heterogenous catalytic materials, but due to the complex and …
Data driven reaction mechanism estimation via transient kinetics and machine learning
Understanding the set of elementary steps and kinetics in each reaction is extremely
valuable to make informed decisions about creating the next generation of catalytic …
valuable to make informed decisions about creating the next generation of catalytic …
Fitting micro-kinetic models to transient kinetics of temporal analysis of product reactors using kinetics-informed neural networks
The temporal analysis of products (TAP) technique produces extensive transient kinetic data
sets, but it is challenging to translate the large quantity of raw data into physically …
sets, but it is challenging to translate the large quantity of raw data into physically …
Internal calibration of transient kinetic data via machine learning
The temporal analysis of products (TAP) reactor provides a vast amount of transient kinetic
information that may be used to describe a variety of chemical features including residence …
information that may be used to describe a variety of chemical features including residence …
Role of surface diffusion in formation of unique reactivity for graphite oxidation: Time-resolved measurements in a pulsed diffusion reactor
Quantification of oxidation kinetics is essential to develop graphitic materials for diverse
applications: from refractories found in gas-cooled nuclear reactors to catalysts needed for …
applications: from refractories found in gas-cooled nuclear reactors to catalysts needed for …
A note on the standard diffusion curve of TAP analysis
T Isaac - arXiv preprint arXiv:2302.03772, 2023 - arxiv.org
arXiv:2302.03772v1 [cs.MS] 7 Feb 2023 Page 1 arXiv:2302.03772v1 [cs.MS] 7 Feb 2023 A
NOTE ON THE STANDARD DIFFUSION CURVE OF TAP ANALYSIS TOBY ISAAC (TISAAC@ANL.GOV) …
NOTE ON THE STANDARD DIFFUSION CURVE OF TAP ANALYSIS TOBY ISAAC (TISAAC@ANL.GOV) …
A Priori Calibration of Transient Kinetics Data via Machine Learning
The temporal analysis of products reactor provides a vast amount of transient kinetic
information that may be used to describe a variety of chemical features including the …
information that may be used to describe a variety of chemical features including the …
Precise composition/kinetic characterization of solid catalysts using temporal analysis of products
Y Wang, G Yablonsky, R Fushimi - 2021 - books.rsc.org
The kinetic properties of a heterogeneous catalyst are markedly influenced by the surface
composition of the catalyst itself as well as the composition of adsorbed species. The …
composition of the catalyst itself as well as the composition of adsorbed species. The …
In-situ studies of catalytic reactions over well-defined model catalysts
Atomic-scale understanding of the elementary processes occurring at catalytic surfaces and
interfaces requires the development of surface science techniques, that could measure the …
interfaces requires the development of surface science techniques, that could measure the …