In the development of new systems for asymmetric synthesis it has always been a big
challenge to obtain optically active compounds with good yields and selectivities. For this …

Vor allem bei enantioselektiven Synthesen werden vicinale Diamine (1, 2‐Diamine) 1 und
Verbindungen, die auf einfachem Weg aus diesen erhalten werden können–wie 1, 2 …

Over the past decade there has been a great surge of interest in enantioselective synthesis
which has led to an increased demand for accurate, reliable, and con-venient methods of …

A comprehensive overview of the use of NMR spectroscopy for chiral discrimination
Discrimination of Chiral Compounds Using NMR Spectroscopy concisely covers the broad …

Chiral framework: Chiral amines with pyrrolidine frameworks catalyze the enantioselective
conjugate addition of a wide range of aldehydes to various vinyl sulfones and vinyl …

H. 6. Reactions with a,~-ethylenic acetals and ketals 11.7. Directing strength of the acetal
template 11.8. Miscellaneous cleavages IlL REACTIONS WITHOUT RING CLEAVAGE III. 1 …

The synthesis of nitronyl and imino nitroxides has been reexamined with the aim of both
increasing yields and of offering opportunities for new structures. The conditions for the …

Carbometalation of a 1, 2-disubstituted olefin leads to the formation of a new organometallic
species bearing two contigu-ous stereogenic centers. 1 Although the carbolithiation reaction …

Chiral molecules are widely used in many fields of research and so practically simple,
accurate methods to measure their enantiopurities are required. This review's initial focus is …

A new reagent is described for the determination of the enantiomeric excess of chiral
alcohols. This derivatizing agent (22) is a diazaphospholidine, easily prepared from …