Perfluoroalkylfullerenes

OV Boltalina, AA Popov, IV Kuvychko… - Chemical …, 2015 - ACS Publications
Perfluoroalkylfullerenes | Chemical Reviews ACS ACS Publications C&EN CAS Find my
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Electrophilic trifluoromethylation of dimetallofullerene anions en route to air-stable single-molecule magnets with high blocking temperature of magnetization

Y Wang, G Velkos, NJ Israel… - Journal of the …, 2021 - ACS Publications
Lanthanide dimetallofullerenes with single-electron M–M bonds are an important class of
single molecular magnets and qubit candidates, but stabilization of their unique electronic …

Ethynylene-linked donor–acceptor alternating copolymers

WA Braunecker, SD Oosterhout, ZR Owczarczyk… - …, 2013 - ACS Publications
Controlling steric interactions between neighboring repeat units in donor–acceptor (D–A)
alternating copolymers can positively impact morphologies and intermolecular electronic …

Photobleaching dynamics in small molecule vs. polymer organic photovoltaic blends with 1, 7-bis-trifluoromethylfullerene

LE Garner, VN Viswanathan, DH Arias… - Journal of Materials …, 2018 - pubs.rsc.org
Two organic photovoltaic (OPV) donor materials (one polymer and one small molecule) are
synthesized from the same constituent building blocks, namely thiophene units …

Synthesis and characterization of pentafluorosulfanyl-functionalized fullerenes

SY Qing, NJ DeWeerd, AV Matsnev, SH Strauss… - Journal of Fluorine …, 2018 - Elsevier
Fullerene C 60 was reacted with SF 5 CF 2 CF 2 I and SF 5 CF 2 I in the presence of Cu
powder at 140–180° C resulting in the successful production of the first pentafluorosulfanyl …

Trifluoromethylation of fullerenes: kinetic and thermodynamic control

DV Ignat'eva, AA Goryunkov, IN Ioffe… - The Journal of Physical …, 2013 - ACS Publications
We present a survey and theoretical interpretation of the experimental results on
trifluoromethylation of fullerenes. A thermodynamic model has been developed to describe …

Core Perylene Diimide Designs via Direct Bay‐ and ortho‐(Poly)trifluoromethylation: Synthesis, Isolation, X‐ray Structures, Optical and Electronic Properties

TT Clikeman, EV Bukovsky, XB Wang… - European Journal of …, 2015 - Wiley Online Library
We developed an efficient solvent‐and catalyst‐free direct polytrifluoromethylation of solid
perylene‐3, 4, 9, 10‐tetracarboxylic dianhydride that produced a new family of (poly) …

Substituent effects in a series of 1, 7-C 60 (RF) 2 compounds (RF= CF 3, C 2 F 5, nC 3 F 7, iC 3 F 7, nC 4 F 9, sC 4 F 9, nC 8 F 17): electron affinities, reduction …

IV Kuvychko, JB Whitaker, BW Larson, TC Folsom… - Chemical …, 2012 - pubs.rsc.org
A series of seven structurally-similar compounds with different pairs of RF groups were
prepared, characterized spectroscopically, and studied by electrochemical methods (cyclic …

Inter‐Fullerene Electronic Coupling Controls the Efficiency of Photoinduced Charge Generation in Organic Bulk Heterojunctions

BW Larson, OG Reid, DC Coffey… - Advanced Energy …, 2016 - Wiley Online Library
Photoinduced charge generation (PCG) dynamics are notoriously difficult to correlate with
specific molecular properties in device relevant polymer: fullerene organic photovoltaic …

Perfluoroalkyl [70]-Fullerenes as Robust Highly-Luminescent Fluorocarbons, or Position of One CF3 Group Matters

KP Castro, Y Jin, JJ Rack, SH Strauss… - The Journal of …, 2013 - ACS Publications
The photophysical properties of two C70 (CF3) 8 and three C70 (CF3) 10 isomers were
studied using steady-state and time-resolved absorption and fluorescence spectroscopy …