Transition-metal-catalyzed cross-couplings through carbene migratory insertion

Y Xia, D Qiu, J Wang - Chemical reviews, 2017 - ACS Publications
Transition-metal-catalyzed cross-coupling reactions have been well-established as
indispensable tools in modern organic synthesis. One of the major research goals in cross …

Recent Developments in Pd‐Catalyzed Reactions of Diazo Compounds

Y Zhang, J Wang - European Journal of Organic Chemistry, 2011 - Wiley Online Library
Pd‐catalyzed reactions of diazo compounds result in unique transformations that are distinct
from those of traditional processes catalyzed by RhII or CuI catalysts. Pd carbene migratory …

Tosylhydrazones: new uses for classic reagents in palladium‐catalyzed cross‐coupling and metal‐free reactions

J Barluenga, C Valdés - Angewandte Chemie International …, 2011 - Wiley Online Library
Tosylhydrazones are useful synthetic intermediates that have been used in organic
chemistry for almost 60 years. The recent discovery of a palladium‐catalyzed cross‐coupling …

[PDF][PDF] N-tosylhydrazones as reagents for cross-coupling reactions: a route to polysubstituted olefins

J Barluenga, P Moriel, C Valdés… - … EDITION IN ENGLISH-, 2007 - academia.edu
Pd-catalyzed cross-coupling reactions can be considered nowadays to be the most reliable
methodology for the formation of C (sp2) ÀC (sp2) bonds.[1] These types of reactions find …

Enantioselective synthesis of atropisomeric vinyl arene compounds by palladium catalysis: a carbene strategy

J Feng, B Li, Y He, Z Gu - Angewandte Chemie International …, 2016 - Wiley Online Library
Enantioselective Synthesis of Atropisomeric Vinyl Arene Compounds by Palladium Catalysis:
A Carbene Strategy - Feng - 2016 - Angewandte Chemie International Edition - Wiley Online …

Palladium-catalyzed carbene migratory insertion using conjugated ene–yne–ketones as carbene precursors

Y Xia, S Qu, Q Xiao, ZX Wang, P Qu… - Journal of the …, 2013 - ACS Publications
Palladium-catalyzed cross-coupling reactions between benzyl, aryl, or allyl bromides and
conjugated ene–yne–ketones lead to the formation of 2-alkenyl-substituted furans. This …

Pd-catalyzed carbonylation of diazo compounds at atmospheric pressure: a catalytic approach to ketenes

Z Zhang, Y Liu, L Ling, Y Li, Y Dong… - Journal of the …, 2011 - ACS Publications
The carbonylation of carbenes through catalytic cycles is highly desirable due to the
importance of ketene-mediated reactions in organic synthesis. In this investigation, a highly …

Visible-Light-Induced In Situ Generation of Fischer-Type Copper Carbene Complexes from Acylsilanes and Its Application to Catalytic [4 + 1] Cycloaddition with …

T Takeuchi, T Aoyama, K Orihara, K Ishida… - Organic …, 2021 - ACS Publications
A novel methodology for in situ generation of Fischer-type metal–carbene complexes was
developed. Photoirradiation to a mixture of an acylsilane and a cationic copper complex …

Palladium-catalyzed cross-coupling of α-diazocarbonyl compounds with arylboronic acids

C Peng, Y Wang, J Wang - Journal of the American Chemical …, 2008 - ACS Publications
Palladium-Catalyzed Cross-Coupling of α-Diazocarbonyl Compounds with Arylboronic
Acids | Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find …

Pd-Catalyzed CC Double-Bond Formation by Coupling of N-Tosylhydrazones with Benzyl Halides

Q Xiao, J Ma, Y Yang, Y Zhang, J Wang - Organic Letters, 2009 - ACS Publications
Pd-Catalyzed C═C Double-Bond Formation by Coupling of N-Tosylhydrazones with Benzyl
Halides | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log In …